Evidence map›Paper›PMID 36152311›Full record

ArticleChemistry (Weinheim an der Bergstrasse, Germany)2023

Metal Nodes of Metal-Organic Frameworks can Activate Molecular Hydrogen.

Arianna Melillo, Antonio Franconetti, Mercedes Alvaro, Belen Ferrer, Hermenegildo Garcia

Open access · hybridAbstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
0.9field-weighted citation impact, top 30% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed, 13 citations in OpenAlex.

  1. Metal Nodes of Metal-Organic Frameworks can Activate Molecular Hydrogen.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors at 3 institutions in 1 country.

Arianna MelilloDepartamento de Química, Universitat Politècnica de València, Camino de Vera s/n, 46022, Valencia, Spain.
Antonio FranconettiCIC BioGUNE, Bizkaia Science and Technology Park, Building 800, 48160, Derio, Bizkaia, Spain.
Mercedes AlvaroDepartamento de Química, Universitat Politècnica de València, Camino de Vera s/n, 46022, Valencia, Spain.
Belen FerrerDepartamento de Química, Universitat Politècnica de València, Camino de Vera s/n, 46022, Valencia, Spain.
Hermenegildo GarciaDepartamento de Química, Universitat Politècnica de València, Camino de Vera s/n, 46022, Valencia, Spain.
Universitat Politècnica de València · ESEuskadiko Parke Teknologikoa · ESInstituto de Tecnología Química · ES

Funding

Generalitat Valenciana Prometeo 2021-083Ministerio de Ciencia e Innovación RTI2018-098237-CO2-R1 and Severo Ochoa
6 · The paper itself

Abstract

Hydrogenation of multiple bonds are among the most general and important organic reactions. Typical heterogeneous catalysts are based on transition metal nanoparticles, including noble metals. Data are presented here showing that metal nodes of MIL-101(Cr) and UiO-66 in the absence of occluded metal nanoparticles can promote hydrogenation of polarized X=Y double bonds of nitro and carbonyl groups. The catalytic activity is a function of the composition of the metal node and the organic linker. It is proposed that the reaction mechanism is based on the operation of frustrated Lewis acid/base pairs.

Indexed as

catalytic hydrogenationheterogeneous catalysismetal-organic frameworks as catalystsUiO-66 as hydrogenation catalyst

Identifiers

PMID36152311
PMCPMC10100435
OpenAlexW4296954320

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.