Synthesis of Iron(II) Clathrochelate-Based Poly(vinylene sulfide) with Tetraphenylbenzene Bridging Units and Their Selective Oxidation into Their Corresponding Poly(vinylene sulfone) Copolymers: Promising Materials for Iodine Capture.

Noorullah Baig, Suchetha Shetty, Sameh S Habib, Ali A Husain, Saleh Al-Mousawi, Bassam Alameddine

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Article in Polymers, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

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4citing papers in PubMed

1.7field-weighted citation impact, top 17% of its field

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4 citing papers in PubMed, 22 citations in OpenAlex.

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6 authors at 2 institutions in 1 country.

Noorullah BaigDepartment of Mathematics and Natural Sciences, Gulf University for Science and Technology, Hawally 32093, Kuwait.ORCID 0000-0002-9193-1171

Suchetha ShettyDepartment of Mathematics and Natural Sciences, Gulf University for Science and Technology, Hawally 32093, Kuwait.ORCID 0000-0003-2618-5384

Sameh S HabibDepartment of Chemistry Kuwait City, Kuwait University, P.O. Box 12613, Safat 13060, Kuwait.

Ali A HusainDepartment of Chemistry Kuwait City, Kuwait University, P.O. Box 12613, Safat 13060, Kuwait.

Saleh Al-MousawiDepartment of Chemistry Kuwait City, Kuwait University, P.O. Box 12613, Safat 13060, Kuwait.

Bassam AlameddineDepartment of Mathematics and Natural Sciences, Gulf University for Science and Technology, Hawally 32093, Kuwait.ORCID 0000-0002-7881-4392

Gulf University for Science & Technology · KWKuwait University · KW

Funding

Federal Ministry of Education and Research 01DL20003Kuwait Foundation for the Advancement of Sciences PN18-14SC-03

6 · The paper itself

Abstract

The development of a simple and efficient synthetic methodology to engineer functional polymer materials for gas adsorption is necessary due to its relevance for various applications. Herein, we report the synthesis of metalorganic poly(vinylene sulfide) copolymers CTP1-3 with iron(II) clathrochelate of various side groups connected by tetraphenylbenzene units. CTP1-3 were subsequently oxidized into their respective poly(vinylene sulfone) copolymers CTP4-6 under green reaction conditions. The target copolymers CTP1-6 were characterized using various instrumental analysis techniques. Examination of the iodine adsorption properties of the copolymers revealed high iodine uptake properties, reaching 2360 mg g

Indexed as

click-reactioniodine adsorptionmetalorganic polymerone-pot synthesispoly(vinylene sulfide)poly(vinylene sulfone)

Identifiers

PMID36145872

DOI10.3390/polym14183727

PMCPMC9504420

OpenAlexW4296112438

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