ArticleNanoscale advances2020
Regioselective thiocyanation of corroles and the synthesis of gold nanoparticle-corrole assemblies.
Article in Nanoscale advances, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed, 9 citations in OpenAlex.
- Assessment of the performance of six indices in predicating the aromaticity of planar porphyrinoids.Journal of molecular modeling · 2023Article
- Synthesis, Characterization, and the N Atom Transfer Reactivity of a Nitridochromium(V) Complex Stabilized by a Corrolato Ligand.ACS omega · 2022Article
- Corroles and Hexaphyrins: Synthesis and Application in Cancer Photodynamic Therapy.Molecules (Basel, Switzerland) · 2020Review
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Authors and funding
7 authors at 2 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Herein we demonstrate a synthetic protocol for the regioselective thiocyanation of corroles. To the best of our knowledge, thiocyanato appended corrole has never been reported earlier. The resulting thiocyanato appended corrole turned out to be a good corrole based precursor for the facile synthesis of thiol protected gold nanoparticles (Au NPs). The ligand system acts as a good bidentate framework and passivates the gold surface. A strong electronic interaction between the corrole and the gold nanoparticles is manifested by their unique photo physical properties and it also confirms that the binding through β-substitutions has a more pronounced effect even though the corrole rings are face-off to the gold surface.
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Registered trials
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