ArticleChem2022
Ternary host-guest complexes with rapid exchange kinetics and photoswitchable fluorescence.
Article in Chem, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
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Who cites it
9 citing papers in PubMed, 47 citations in OpenAlex.
- Microporous Self-Assembled Pd(II) Tetrahedral Cages for Rapid and Reversible Multi-Phase Sequestration of Iodine and Methyl Iodide.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Article
- Photoresponsive luminescent single-molecule magnets based on dysprosium-anthracene complexes: regulating the de-dimerization temperature of the photocycloaddition product by co-ligand.Chemical science · 2025Article
- Azobisheteroarene photoswitches based on isoxazoles and pyrazoles: tunable photostationary states, thermal relaxation and sensitization under confinement.Chemical science · 2025Article
- Self-Assembled Pd(II) Nano-Adsorbents for Iodine and Methyl Iodide Capture in Vapor and Aqueous Phases.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
- Guest Encapsulation Alters the Thermodynamic Landscape of a Coordination Host.Journal of the American Chemical Society · 2023Article
- Anionic Templates Drive Conversion between a ZnJournal of the American Chemical Society · 2023Article
- Altering the Properties of Spiropyran Switches Using Coordination Cages with Different Symmetries.Journal of the American Chemical Society · 2022Article
- Reconstructing reactivity in dynamic host-guest systems at atomistic resolution: amide hydrolysis under confinement in the cavity of a coordination cage.Chemical science · 2022Article
Corrections and comments
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Authors and funding
9 authors at 2 institutions in 2 countries.
Funding
Abstract
Confinement within molecular cages can dramatically modify the physicochemical properties of the encapsulated guest molecules, but such host-guest complexes have mainly been studied in a static context. Combining confinement effects with fast guest exchange kinetics could pave the way toward stimuli-responsive supramolecular systems-and ultimately materials-whose desired properties could be tailored "on demand" rapidly and reversibly. Here, we demonstrate rapid guest exchange between inclusion complexes of an open-window coordination cage that can simultaneously accommodate two guest molecules. Working with two types of guests, anthracene derivatives and BODIPY dyes, we show that the former can substantially modify the optical properties of the latter upon noncovalent heterodimer formation. We also studied the light-induced covalent dimerization of encapsulated anthracenes and found large effects of confinement on reaction rates. By coupling the photodimerization with the rapid guest exchange, we developed a new way to modulate fluorescence using external irradiation.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.