Evidence map›Paper›PMID 36129127›Full record

ArticleChemistry (Weinheim an der Bergstrasse, Germany)2023

Carbodicarbenes and Striking Redox Transitions of their Conjugate Acids: Influence of NHC versus CAAC as Donor Substituents.

Ramapada Dolai, Rahul Kumar, Benedict J Elvers, Pradeep Kumar Pal, Benson Joseph, Rina Sikari, Mithilesh Kumar Nayak, Avijit Maiti, Tejender Singh, Nicolas Chrysochos and 8 more

Open access · greenAbstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
2.0field-weighted citation impact, top 14% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed, 19 citations in OpenAlex.

  1. Bent N-Heterocyclic Allenes From a Well-Defined Titanium Vinylidene Complex.Angewandte Chemie (International ed. in English) · 2026
    Article
  2. Article
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

18 authors at 5 institutions in 3 countries.

Ramapada DolaiTata Institute of Fundamental Research Hyderabad Gopanpally, Hyderabad, 500046, Telangana, India.
Rahul KumarTata Institute of Fundamental Research Hyderabad Gopanpally, Hyderabad, 500046, Telangana, India.
Benedict J ElversInstitut für Biochemie, Universität Greifswald, Felix-Hausdorff-Strasse 4, 17489, Greifswald, Germany.
Pradeep Kumar PalInternational Institute of Information Technology Gachibowli, Hyderabad, 500032, India.
Benson JosephTata Institute of Fundamental Research Hyderabad Gopanpally, Hyderabad, 500046, Telangana, India.
Rina SikariTata Institute of Fundamental Research Hyderabad Gopanpally, Hyderabad, 500046, Telangana, India.
Mithilesh Kumar NayakTata Institute of Fundamental Research Hyderabad Gopanpally, Hyderabad, 500046, Telangana, India.
Avijit MaitiTata Institute of Fundamental Research Hyderabad Gopanpally, Hyderabad, 500046, Telangana, India.
Tejender SinghTata Institute of Fundamental Research Hyderabad Gopanpally, Hyderabad, 500046, Telangana, India.
Nicolas ChrysochosTata Institute of Fundamental Research Hyderabad Gopanpally, Hyderabad, 500046, Telangana, India.
Arumugam JayaramanInstitute of Inorganic Chemistry and Institute for Sustainable Chemistry & Catalysis with Boron (ICB), Julius-Maximilians-Universität Würzburg, Am Hubland, 97074, Würzburg, Germany.
Ivo KrummenacherInstitute of Inorganic Chemistry and Institute for Sustainable Chemistry & Catalysis with Boron (ICB), Julius-Maximilians-Universität Würzburg, Am Hubland, 97074, Würzburg, Germany.
Jagannath MondalTata Institute of Fundamental Research Hyderabad Gopanpally, Hyderabad, 500046, Telangana, India.
U Deva PriyakumarInternational Institute of Information Technology Gachibowli, Hyderabad, 500032, India.
Holger BraunschweigInstitute of Inorganic Chemistry and Institute for Sustainable Chemistry & Catalysis with Boron (ICB), Julius-Maximilians-Universität Würzburg, Am Hubland, 97074, Würzburg, Germany.
Cem B YildizDepartment of Aromatic and Medicinal Plants, Aksaray University, Aksaray, 68100, Turkey.
Carola SchulzkeInstitut für Biochemie, Universität Greifswald, Felix-Hausdorff-Strasse 4, 17489, Greifswald, Germany.
Anukul JanaTata Institute of Fundamental Research Hyderabad Gopanpally, Hyderabad, 500046, Telangana, India.ORCID http://orcid.org/0000-0002-1657-1321
TIFR Centre for Interdisciplinary Sciences · INUniversity of Würzburg · DEInternational Institute of Information Technology · INUniversitätsmedizin Greifswald · DEAksaray University · TR

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Herein, a new type of carbodicarbene (CDC) comprising two different classes of carbenes is reported; NHC and CAAC as donor substituents and compare the molecular structure and coordination to Au(I)Cl to those of NHC-only and CAAC-only analogues. The conjugate acids of these three CDCs exhibit notable redox properties. Their reactions with [NO][SbF

Indexed as

carbene ligandscarbodicarbenecyclic voltammetryoxidationreduction

Identifiers

PMID36129127
PMCPMC10100033
OpenAlexW4296962495

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC-ND
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.