ReviewChemical communications (Cambridge, England)2022
Small molecule activation with bimetallic systems: a landscape of cooperative reactivity.
Review in Chemical communications (Cambridge, England), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 18 papers.
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Who cites it
18 citing papers in PubMed.
- Defined Dinuclear Nickel Sites on Mesoporous Silica Translate Molecular Surface Mimics to Heterogeneous Catalysis.Angewandte Chemie (International ed. in English) · 2026Article
- A heterobimetallic journey from ambiphilic Ti phosphide to nucleophilic Ti/Ir phosphinidene.Chemical science · 2026Article
- Manganese(II) and Magnesium(II) Analogies in Iridium Hydride Coordination Chemistry.Inorganic chemistry · 2026Article
- Cooperative reactivity of halomethanes and -silanes at an A-frame complex: transannular additionChemical science · 2026Article
- Activation of Dioxygen via Neodymium-Alkali Metal Clusters.Journal of the American Chemical Society · 2026Article
- Leveraging Chelating Amido Ligands to Support Metal-Metal Bonding in Dinuclear Cr(II) Complexes.Inorganic chemistry · 2026Article
- Probing Structural Diversity in a Series of Perhydrocarbyl Heterobimetallic Complexes Associating Tantalum and 3d (Cr, Mn, Fe, Co, Ni) Transition Metals.Inorganic chemistry · 2025Article
- Mechanistic Studies of Alkyl Chloride Acetoxylation by Pt-Sb Complexes.Organometallics · 2025Article
- Isolobal Cationic Iridium Dihydride and Dizinc Complexes: A Dual Role for the ZnR Ligand Enhances HInorganic chemistry · 2024Article
- Synthesis of Quinoline-Based Pt-Sb Complexes with L- or Z-Type Interaction: Ligand-Controlled Redox via Anion Transfer.Organometallics · 2024Article
- Article
- Welcoming Neighbour or Inhospitable Host? Selective Second Metal Binding in 5- and 6-Phospha-Substituted Bpy Ligands.Molecules (Basel, Switzerland) · 2024Article
- Two active species from a single metal halide precursor: a case study of highly productive Mn-catalyzed dehydrogenation of amine-boranesChemical science · 2024Article
- Ligand Postsynthetic Functionalization with Fluorinated Boranes and Implications in Hydrogenation Catalysis.ACS catalysis · 2023Article
- Cycloaddition and C-S Bond Cleavage Processes in Reactions of Heterometallic Phosphinidene-Bridged MoRe and MoMn Complexes with Alkynes and Phenyl Isothiocyanate.Organometallics · 2023Article
- Formation of Heterobimetallic Complexes by Addition of dInorganic chemistry · 2023Article
- Reactions of Heterometallic Phosphinidene-Bridged MoMn and MoRe Complexes with Sulfur and Selenium: From Chalcogenophosphinidene- to Trithiophosphonate-Bridged Derivatives.Inorganic chemistry · 2023Article
- Polarized Au(I)/Rh(I) bimetallic pairs cooperatively trigger ligand non-innocence and bond activation.Dalton transactions (Cambridge, England : 2003) · 2023Article
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
There is growing interest in the design of bimetallic cooperative complexes, which have emerged due to their potential for bond activation and catalysis, a feature widely exploited by nature in metalloenzymes, and also in the field of heterogeneous catalysis. Herein, we discuss the widespread opportunities derived from combining two metals in close proximity, ranging from systems containing multiple M-M bonds to others in which bimetallic cooperation occurs even in the absence of M⋯M interactions. The choice of metal pairs is crucial for the reactivity of the resulting complexes. In this context, we describe the prospects of combining not only transition metals but also those of the main group series, which offer additional avenues for cooperative pathways and reaction discovery. Emphasis is given to mechanisms by which bond activation occurs across bimetallic structures, which is ascribed to the precise synergy between the two metal atoms. The results discussed herein indicate a future landscape full of possibilities within our reach, where we anticipate that bimetallic synergism will have an important impact in the design of more efficient catalytic processes and the discovery of new catalytic transformations.
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