ReviewChemical science2022
Organic radicals with inversion of SOMO and HOMO energies and potential applications in optoelectronics.
Review in Chemical science, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
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Who cites it
17 citing papers in PubMed.
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- Aromaticity-Engineered Open-Shell Radical Anions for Air-Stable Doublet Emission in N-Annulated Perylene Diimide.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Unraveling the coordination isomerism by ligand hyperfine NMR shifts.Chemical science · 2026Article
- An undecacyclic carbon-centered hydrocarbon radical: synthesis and investigation.Beilstein journal of organic chemistry · 2026Article
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- Cyclopenta-Fused Polyaromatic Hydrocarbon (CP-PAH) Radicals: Synthesis, Characterization, and Quantum Chemical Calculations.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- A Radical-Cationic Covalent Organic Framework to Accelerate Polysulfide Conversion for Long-Durable Lithium-Sulfur Batteries.Journal of the American Chemical Society · 2025Article
- Robust organic radical cations with near-unity absorption across solar spectrum.Nature communications · 2025Article
- Synthesis of a Stable Radical Cation of Bis-Tert-Butyl Ethylenedioxythiophene and its Application as a Dopant in Organic Semiconductors.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
- Multireference Theory of Scanning Tunneling Spectroscopy Beyond One-Electron Molecular Orbitals: Can We Image Molecular Orbitals?Journal of the American Chemical Society · 2025Article
- Factors Controlling Diastereoselectivity and Reactivity in the Catalytic Aerobic Carbooxygenation of (E)-2-Fluoro-3-aryl-allyl Nitroacetates.Chemistry, an Asian journal · 2025Article
- Magnesium sulfate in oxidative stress-associated pathologies: clinical, cellular, and molecular perspectives.Biophysical reviews · 2025Review
- π-Extended 4,5-Fused Bis-Fluorene: Highly Open-Shell Compounds and their Cationic Tetrathiafulvalene Derivatives.Angewandte Chemie (International ed. in English) · 2024Article
- Non-Aufbau electronic structure in radical enzymes and control of the highly reactive intermediates.Chemical science · 2024Article
- In Vitro Evaluation and In Silico Calculations of the Antioxidant and Anti-Inflammatory Properties of Secondary Metabolites fromMolecules (Basel, Switzerland) · 2023Article
- Thermally UltrarobustJournal of the American Chemical Society · 2023Article
Corrections and comments
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Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Organic radicals possessing an electronic configuration in which the energy of the singly occupied molecular orbital (SOMO) is below the highest doubly occupied molecular orbital (HOMO) level have recently attracted significant interest, both theoretically and experimentally. The peculiar orbital energetics of these SOMO-HOMO inversion (SHI) organic radicals set their electronic properties apart from the more common situation where the SOMO is the highest occupied orbital of the system. This review gives a general perspective on SHI, with key fundamental aspects regarding the electronic and structural factors that govern this particular electronic configuration in organic radicals. Selected examples of reported compounds with SHI are highlighted to establish molecular guidelines for designing this type of radical, and to showcase the potential of SHI radicals in organic spintronics as well as for the development of more stable luminescent radicals for OLED applications.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.