Evidence map›Paper›PMID 36115857›Full record

ArticleNature communications2022

Main-chain engineering of polymer photocatalysts with hydrophilic non-conjugated segments for visible-light-driven hydrogen evolution.

Chih-Li Chang, Wei-Cheng Lin, Li-Yu Ting, Chin-Hsuan Shih, Shih-Yuan Chen, Tse-Fu Huang, Hiroyuki Tateno, Jayachandran Jayakumar, Wen-Yang Jao, Chen-Wei Tai and 8 more

Abstract read
In one paragraph

Article in Nature communications, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.

0numbers the graph read from it
0cells of the map it votes in
15citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

15 citing papers in PubMed.

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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

18 authors.

Chih-Li ChangDepartment of Chemical Engineering, National Tsing Hua University, Hsinchu, 300044, Taiwan.ORCID http://orcid.org/0000-0001-9497-7186
Wei-Cheng LinDepartment of Chemical Engineering, National Tsing Hua University, Hsinchu, 300044, Taiwan.
Li-Yu TingDepartment of Chemical Engineering, National Tsing Hua University, Hsinchu, 300044, Taiwan.
Chin-Hsuan ShihDepartment of Engineering Science, National Cheng Kung University, Tainan, 701401, Taiwan.
Shih-Yuan ChenEnergy Catalyst Technology Group, Energy Process Research Institute, National Institute of Advanced Industrial Science and Technology, Ibaraki, 305-8559, Japan.ORCID http://orcid.org/0000-0002-7093-2511
Tse-Fu HuangDepartment of Chemical Engineering, National Tsing Hua University, Hsinchu, 300044, Taiwan.
Hiroyuki TatenoEnergy Catalyst Technology Group, Energy Process Research Institute, National Institute of Advanced Industrial Science and Technology, Ibaraki, 305-8559, Japan.ORCID http://orcid.org/0000-0003-2395-2197
Jayachandran JayakumarDepartment of Chemical Engineering, National Tsing Hua University, Hsinchu, 300044, Taiwan.
Wen-Yang JaoDepartment of Chemical Engineering, National Tsing Hua University, Hsinchu, 300044, Taiwan.
Chen-Wei TaiDepartment of Chemical Engineering, National Tsing Hua University, Hsinchu, 300044, Taiwan.
Che-Yi ChuDepartment of Chemical Engineering, National Chung Hsing University, Taichung, 402202, Taiwan.
Chin-Wen ChenDepartment of Molecular Science and Engineering, National Taipei University of Technology, Taipei, 106344, Taiwan.ORCID http://orcid.org/0000-0001-6966-7573
Chi-Hua YuDepartment of Engineering Science, National Cheng Kung University, Tainan, 701401, Taiwan.ORCID http://orcid.org/0000-0001-9445-3358
Yu-Jung LuResearch Center for Applied Sciences, Academia Sinica, Taipei, 115024, Taiwan.ORCID http://orcid.org/0000-0002-3932-653X
Chi-Chang HuDepartment of Chemical Engineering, National Tsing Hua University, Hsinchu, 300044, Taiwan.ORCID http://orcid.org/0000-0002-4308-8474
Ahmed M ElewaDepartment of Chemical Engineering, National Tsing Hua University, Hsinchu, 300044, Taiwan.ORCID http://orcid.org/0000-0001-8943-5710
Takehisa MochizukiEnergy Catalyst Technology Group, Energy Process Research Institute, National Institute of Advanced Industrial Science and Technology, Ibaraki, 305-8559, Japan.
Ho-Hsiu ChouDepartment of Chemical Engineering, National Tsing Hua University, Hsinchu, 300044, Taiwan. hhchou@mx.nthu.edu.tw.ORCID http://orcid.org/0000-0003-3777-2277

Funding

Ministry of Science and Technology, Taiwan (Ministry of Science and Technology of Taiwan) MOST 110-2622-8-007-011-Ministry of Science and Technology, Taiwan (Ministry of Science and Technology of Taiwan) MOST 111-2221-E-007-004-Ministry of Science and Technology, Taiwan (Ministry of Science and Technology of Taiwan) MOST 111-2628-E-007-009-
6 · The paper itself

Abstract

Photocatalytic water splitting is attracting considerable interest because it enables the conversion of solar energy into hydrogen for use as a zero-emission fuel or chemical feedstock. Herein, we present a universal approach for inserting hydrophilic non-conjugated segments into the main-chain of conjugated polymers to produce a series of discontinuously conjugated polymer photocatalysts. Water can effectively be brought into the interior through these hydrophilic non-conjugated segments, resulting in effective water/polymer interfaces inside the bulk discontinuously conjugated polymers in both thin-film and solution. Discontinuously conjugated polymer with 10 mol% hexaethylene glycol-based hydrophilic segments achieves an apparent quantum yield of 17.82% under 460 nm monochromatic light irradiation in solution and a hydrogen evolution rate of 16.8 mmol m

Identifiers

PMID36115857
PMCPMC9482619

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.