Evidence map›Paper›PMID 36111586›Full record

ArticleAngewandte Chemie (International ed. in English)2022

Hydrogen-Bond-Modulated Nucleofugality of Se

Sooyoung Park, Amit K Dutta, Carina Allacher, Anton Abramov, Philipp Dullinger, Katerina Kuzmanoska, Daniela Fritsch, Patrick Hitzfeld, Dominik Horinek, Julia Rehbein and 3 more

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.

0numbers the graph read from it
0cells of the map it votes in
7citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

7 citing papers in PubMed.

  1. Article
  2. Review
  3. Article
  4. Article
  5. Catalytic 1,1-diazidation of alkenes.Nature communications · 2024
    Article
  6. Article
  7. Hydrogen-Bond-Modulated Nucleofugality of SeAngewandte Chemie (International ed. in English) · 2022
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

13 authors.

Sooyoung ParkInstitut für Organische Chemie, Universität Regensburg, Universitätstrasse 31, 93053, Regensburg, Germany.
Amit K DuttaInstitut für Organische Chemie, Universität Regensburg, Universitätstrasse 31, 93053, Regensburg, Germany.
Carina AllacherInstitut für Physikalische und Theoretische Chemie, Universität Regensburg, Universitätstrasse 31, 93053, Regensburg, Germany.
Anton AbramovInstitut für Organische Chemie, Universität Regensburg, Universitätstrasse 31, 93053, Regensburg, Germany.
Philipp DullingerInstitut für Organische Chemie, Universität Regensburg, Universitätstrasse 31, 93053, Regensburg, Germany.
Katerina KuzmanoskaInstitut für Organische Chemie, Universität Regensburg, Universitätstrasse 31, 93053, Regensburg, Germany.
Daniela FritschInstitut für Organische Chemie, Universität Regensburg, Universitätstrasse 31, 93053, Regensburg, Germany.
Patrick HitzfeldInstitut für Organische Chemie, Universität Regensburg, Universitätstrasse 31, 93053, Regensburg, Germany.
Dominik HorinekInstitut für Physikalische und Theoretische Chemie, Universität Regensburg, Universitätstrasse 31, 93053, Regensburg, Germany.
Julia RehbeinInstitut für Organische Chemie, Universität Regensburg, Universitätstrasse 31, 93053, Regensburg, Germany.
Patrick NuernbergerInstitut für Physikalische und Theoretische Chemie, Universität Regensburg, Universitätstrasse 31, 93053, Regensburg, Germany.
Ruth M GschwindInstitut für Organische Chemie, Universität Regensburg, Universitätstrasse 31, 93053, Regensburg, Germany.
Alexander BrederInstitut für Organische Chemie, Universität Regensburg, Universitätstrasse 31, 93053, Regensburg, Germany.ORCID http://orcid.org/0000-0003-4899-5919

Funding

Deutsche Forschungsgemeinschaft RTG 2620 - 426795949Deutsche Forschungsgemeinschaft TRR 325 - 444632635H2020 European Research Council grant agreement No. 803426
6 · The paper itself

Abstract

Chemical bond activations mediated by H-bond interactions involving highly electronegative elements such as nitrogen and oxygen are powerful tactics in modern catalysis research. On the contrary, kindred catalytic regimes in which heavier, less electronegative elements such as selenium engage in H-bond interactions to co-activate C-Se σ-bonds under oxidative conditions are elusive. Traditional strategies to enhance the nucleofugality of selenium residues predicate on the oxidative addition of electrophiles onto Se

Indexed as

Hydrogen-BondsNucleofugalityPhotoredox-CatalysisRearrangementsSelenium(III)

Identifiers

PMID36111586
PMCPMC10098919

What OpenQuestion holds

Textmetadata
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Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.