ArticleInorganic chemistry2022
Elucidating Solution-State Coordination Modes of Multidentate Neutral Amine Ligands with Group-1 Metal Cations: Variable-Temperature NMR Studies.
Article in Inorganic chemistry, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Tandem Reactivity of Metal-Carbon and Carbon-Silicon Bonds in Mononuclear α-Silyl Organolithium or Organosodium Complexes Towards CO, COAngewandte Chemie (International ed. in English) · 2026Article
- Reactivity of a Sodium Anion with Alkenes: 1-Electron vs 2-Electron Reductions.Inorganic chemistry · 2025Article
- Reduction of KJournal of the American Chemical Society · 2023Article
- Li vs Na: Divergent Reaction Patterns between Organolithium and Organosodium Complexes and Ligand-Catalyzed Ketone/Aldehyde Methylenation.Journal of the American Chemical Society · 2023Article
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Authors and funding
7 authors.
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Abstract
Multidentate neutral amine ligands play vital roles in coordination chemistry and catalysis. In particular, these ligands are used to tune the reactivity of Group-1 metal reagents, such as organolithium reagents. Most, if not all, of these Group-1 metal reagent-mediated reactions occur in solution. However, the solution-state coordination behaviors of these ligands with Group-1 metal cations are poorly understood, compared to the plethora of solid-state structural studies based on single-crystal X-ray diffraction (SCXRD) studies. In this work, we comprehensively mapped out the coordination modes with Group-1 metal cations for three multidentate neutral amine ligands: tridentate 1,4,7-trimethyl-1,4,7-triazacyclononane (Me
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