ArticleRSC advances2022
Grafting of the gold surface by heterocyclic moieties derived through electrochemical oxidation of amino triazole - an experimental and "
Article in RSC advances, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
1 citing paper in PubMed, 6 citations in OpenAlex.
- Electrografting of Phenyl Phosphate Layers onto Glassy Carbon for Tuning Catalytic Activity toward the Hydrogen Evolution Reaction.Molecules (Basel, Switzerland) · 2024Article
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Authors and funding
1 author at 1 institution in 1 country.
Funding
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Abstract
Surface modification of gold is accomplished by using the aminyl radicals formed through the electrochemical oxidation of the amino-triazole molecule dissolved in organic media (acetonitrile). The electrochemistry of the grafting process and the redox behavior of the grafted heterocyclic layer are similar to those of aliphatic amines. The presence of AT groups on the electrode surface was studied by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) before and after the functionalization process to confirm and prove the formation of a layer on the surface. The capability of the modified surfaces for blocking redox reaction was assessed using a ferrocyanide-ferricyanide redox couple and displayed important differences. The redox probes display a decrease in electron transfer rate. The increase of the charge transfer resistance of the grafted layer is suggestive of a compact layer formation. Furthermore, the Au13 cluster was used to compute BDEs (bond dissociation energies) and a number of other important parameters such as bond strength and length of the interface,
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Registered trials
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