ArticleNational science review2022
Manipulating spatial alignment of donor and acceptor in host-guest MOF for TADF.
Article in National science review, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
What it found
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Who cites it
7 citing papers in PubMed.
- Pressure-Modulated Host-Guest Interactions Boost Effective Blue-Light Emission of MIL-140A Nanocrystals.Nano-micro letters · 2025Article
- Donor-acceptor engineering of a triplet-exciton-optimized MOF photocatalyst for efficient singlet oxygen-mediated oxidation.National science review · 2025Article
- Thermally activated delayed fluorescence materials: innovative design and advanced application in biomedicine, catalysis and electronics.RSC advances · 2025Review
- Unlocking the Potential of Push-Pull Pyridinic Photobases: Aggregation-Induced Excited-State Proton Transfer.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- The Golden Age of Thermally Activated Delayed Fluorescence Materials: Design and Exploitation.Chemical reviews · 2024Review
- Host-Guest Metal-Organic Frameworks-Based Long-Afterglow Luminescence Materials.Molecules (Basel, Switzerland) · 2024Review
- Ultrafast Synthesis of Graphene-Embedded Cyclodextrin-Metal-Organic Framework for Supramolecular Selective Absorbency and Supercapacitor Performance.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2023Article
Corrections and comments
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Authors and funding
6 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Thermally activated delayed fluorescence (TADF) was achieved when electron-rich triphenylene (Tpl) donors were confined to a cage-based porous metal-organic framework (MOF) host (NKU-111) composed of electron-deficient 2,4,6-tri(pyridin-4-yl)-1,3,5-triazine (Tpt) acceptor as the ligand. The spatially separated donor and acceptor molecules in a face-to-face stacking pattern generated strong through-space charge transfer (CT) interactions with a small energy splitting between the singlet and triplet excited states (∼0.1 eV), which enabled TADF. The resulting Tpl@NKU-111 exhibited an uncommon enhanced emission intensity as the temperature increased. Extensive steady-state and time-resolved spectroscopic measurements and first-principles simulations revealed the chemical and electronic structure of this compound in both the ground and low-lying excited states. A double-channel (T
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