ArticleAngewandte Chemie (International ed. in English)2022
Chiral Bismuth-Rhodium Paddlewheel Complexes Empowered by London Dispersion: The C-H Functionalization Nexus.
Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
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Who cites it
14 citing papers in PubMed.
- London Dispersion Governs Stereochemistry, Stability, and Self-Sorting in a System of MJournal of the American Chemical Society · 2026Article
- London Dispersion FavorsThe Journal of organic chemistry · 2026Review
- London Dispersion as a Design Element in Molecular Catalysis.Journal of the American Chemical Society · 2025Review
- Asymmetric C-H Functionalization ofJournal of the American Chemical Society · 2025Article
- Tripodal Silanolate Ligands Expand [MoXJournal of the American Chemical Society · 2025Article
- Article
- Dirhodium Complexes Heterochiral-at-the-Metal Centers: An Alternative Type of Paddlewheel Catalyst for Asymmetric Synthesis.Journal of the American Chemical Society · 2025Article
- Article
- DJournal of the American Chemical Society · 2024Article
- Torsion Effects Beyond the δ Bond and the Role of π Metal-Ligand Interactions.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Catalytic asymmetric carbenoid α-C-H insertion of ether.RSC advances · 2024Review
- Diaryldiazoketones as Effective Carbene Sources for Highly Selective Rh(II)-Catalyzed Intermolecular C-H Functionalization.Journal of the American Chemical Society · 2024Article
- Diruthenium Tetracarboxylate-Catalyzed Enantioselective Cyclopropanation with Aryldiazoacetates.Organometallics · 2023Article
- Chiral Bismuth-Rhodium Paddlewheel Complexes Empowered by London Dispersion: The C-H Functionalization Nexus.Angewandte Chemie (International ed. in English) · 2022Article
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4 authors.
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Abstract
Heterobimetallic [BiRh] tetracarboxylate catalysts endowed with 1,3-disilylated phenylglycine paddlewheels benefit from interligand London dispersion. They were originally designed for asymmetric cyclopropanation but are now shown to perform very well in asymmetric C-H functionalization reactions too. Because of the confined ligand sphere about the derived donor/acceptor carbenes, insertions into unhindered methyl groups are kinetically favored, although methylene units also react with excellent levels of asymmetric induction; even gaseous ethane is a suitable substrate. Moreover, many functional groups in both partners are tolerated. The resulting products are synthetically equivalent to the outcome of traditional asymmetric ester alkylation, allylation, benzylation, propargylation and aldol reactions and therefore constitute a valuable nexus to more conventional chemical logic.
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