ArticleChemical science2022
Hemilabile MIC^N ligands allow oxidant-free Au(i)/Au(iii) arylation-lactonization of γ-alkenoic acids.
Article in Chemical science, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
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Who cites it
12 citing papers in PubMed.
- Synergistic Action of Ascorbic Acid and Readily Accessible NHC^N Ligands for the Oxidation of Gold(I) With Electron-Rich Aryldiazonium Salts.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Oxidant-free Au(I)/Au(III) catalysis: Rational development of hemilabile proximity-guided N-heterocyclic carbenes.Science advances · 2026Article
- Unified Gold(I/III)-Catalyzed Arylative, Vinylative, and Alkynylative Lactonization via Iminium-Directed Cyclization Enabled by Hemilabile Ligands.Organic letters · 2026Article
- Synthesis of (P^N^C)Gold(III) Complexes via Tandem Oxidative Addition/C-H Auration.ACS organic & inorganic Au · 2025Article
- Platform Design Enabling Silver(III) Stabilization ─ The Uprise of AgChemistry (Weinheim an der Bergstrasse, Germany) · 2025Review
- Mechanism of Gold-Catalyzed Arylation-Lactonization: A Density Functional Theory Study on the Role of the (MIC^N)AuCl Complex in Au(I)/Au(III) Catalysis.Inorganic chemistry · 2025Article
- Gold(i) and gold(iii) complexes of triazolyl-functionalised NHCs.RSC advances · 2025Article
- Gold-catalyzed alkenylation and arylation of phosphorothioates.Chemical science · 2023Article
- A Hemilabile NHC-Gold Complex and its Application to the Redox Neutral 1,2-Oxyarylation of Feedstock Alkenes.Angewandte Chemie (International ed. in English) · 2023Article
- L-Shaped Heterobidentate Imidazo[1,5-a]pyridin-3-ylidene (N,C)-Ligands for Oxidant-Free AuAngewandte Chemie (International ed. in English) · 2023Article
- Novel NHC-Based Au(I) Complexes as Precursors of Highly Pure Au(0) Nuggets under Oxidative Conditions.Molecules (Basel, Switzerland) · 2023Article
- Migratory Insertion of CO into a Au-C Bond.Journal of the American Chemical Society · 2022Article
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Oxidant-free Au-catalyzed reactions are emerging as a new synthetic tool for innovative organic transformations. Oxidant-free Au-catalyzed reactions are emerging as a new synthetic tool for innovative organic transformations. Still, a deeper mechanistic understanding is needed for a rational design of these processes. Here we describe the synthesis of two Au(i) complexes bearing bidentated hemilabile MIC^N ligands, [Au
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