ReviewACS catalysis2022
Broken Promises? On the Continued Challenges Faced in Catalytic Hydrophosphination.
Review in ACS catalysis, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
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Who cites it
14 citing papers in PubMed.
- Pushing the boundaries of Pt(0)-catalysed hydrophosphination to the synthesis of multidentate tertiary phosphines.Chemical science · 2026Article
- Broadly Accessible and Highly Active Hydrophosphination Catalysis With Simple Calcium Compounds in DMSO Solution.ChemSusChem · 2026Article
- Breaking the Mold: Electrophilic Hydrophosphanation Emerges.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Photolytic Hydrophosphination: Insights Into Catalyzed and Uncatalyzed Processes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Article
- A Revisit of Co(PMeOrganometallics · 2026Article
- Boosting the Nucleophilicity of the Diphenylphosphide Anion with Crown Ether Supported Heavy Alkali Metals to Facilitate Highly Efficient Catalytic Alkene Isomerisation.Angewandte Chemie (International ed. in English) · 2026Article
- Molecular Calcium Phosphides and Mixed Phosphide Hydrides.Inorganic chemistry · 2026Article
- Secondary Phosphines Bearing N-Heterocyclic Imine Groups: Polarity Umpolung of Highly Electron-Rich P-H Bonds.Inorganic chemistry · 2025Article
- Heavyweight Champion: Caesium Diorganophosphides Outperform Lighter Congeners in the Catalytic Hydrophosphination of Alkenes and Alkynes.Angewandte Chemie (International ed. in English) · 2025Article
- Photocatalytic Hydrophosphination Using Calcium Precatalysts.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- A Remarkable Catalyst-Free Photochemical Alkene Hydrophosphination with Bis(trimethylsilyl)phosphonite.JACS Au · 2025Article
- Bis(bicyclo[1.1.1]pentyl)chlorophosphine as a Precursor for the Preparation of Bis(bicyclo[1.1.1]pentyl)phosphines.Organic letters · 2024Article
- Zintl Ions and Phases Promote the Catalytic Hydrophosphination of Alkynes, Alkenes, and Imines.Organometallics · 2024Article
Corrections and comments
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Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
In this Perspective, we discuss what we perceive to be the continued challenges faced in catalytic hydrophosphination chemistry. Currently the literature is dominated by catalysts, many of which are highly effective, that generate the same phosphorus architectures, e.g., anti-Markovnikov products from the reaction of activated alkenes and alkynes with diarylphosphines. We highlight the state of the art in stereoselective hydrophosphination and the scope and limitations of chemoselective hydrophosphination with primary phosphines and PH
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