ArticleACS catalysis2022
Boron-Catalyzed, Diastereo- and Enantioselective Allylation of Ketones with Allenes.
Article in ACS catalysis, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed.
- Mechanistic elucidation of the uncatalyzed allylation of carbonyl compounds: a combined DFT and nudged elastic band study.Journal of molecular modeling · 2026Article
- Cu-Catalyzed dynamic kinetic asymmetric allylation enabled enantioselective assembly of sterically congested triaryl tertiary alcohols.Nature communications · 2026Article
- Room-temperature hydrogen storage of boron nanoclusters.Nature nanotechnology · 2026Article
- Formally Stereoretentive SJournal of the American Chemical Society · 2025Article
- Recent Advances in Asymmetric Catalysis Using p-Block Elements.Angewandte Chemie (International ed. in English) · 2024Review
- Group 13 exchange and transborylation in catalysis.Beilstein journal of organic chemistry · 2023Review
- Selective CspSynthesis · 2022Article
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Authors and funding
8 authors.
Funding
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Abstract
The diastereo- and enantioselective allylation of ketones remains a synthetic challenge, with transition metal catalysis offering the most applied methods. Here, a boron-catalyzed allylation of ketones with allenes is presented. Excellent yield, regioselectivity, and diastereoselectivity were found across functionalized substrates. The reaction was further developed to accommodate an enantioenriched boron catalyst and thus gave asymmetric ketone allylation in good yield, diastereoselectivity, and enantioselectivity. Mechanistic studies supported a hydroboration-allylation-transborylation pathway.
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