ArticleAngewandte Chemie (International ed. in English)2022
Pseudo-heterolepticity in Low-Symmetry Metal-Organic Cages.
Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed.
- Orientational Self-Sorting in Octahedral Coordination Cages Based on Small, Heteroditopic N-Donor Ligands.Inorganic chemistry · 2026Article
- A Low-Symmetry FeChemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Stereoselective self-assembly of cis- and trans- [PtCommunications chemistry · 2025Article
- Low Symmetry Cage Complexes Formed by Metalation of Symmetric Hexa-Cationic Organic Cages.Angewandte Chemie (International ed. in English) · 2025Article
- Single-Step Synthesis of a Heterometallic [CuAngewandte Chemie (International ed. in English) · 2025Article
- Selection of self-assembled configurational isomers from a dynamic library via a multivariant optimization process.Nature communications · 2025Article
- Beyond symmetric self-assembly and effective molarity: unlocking functional enzyme mimics with robust organic cages.Beilstein journal of organic chemistry · 2025Article
- High-order layered self-assembled multicavity metal--organic capsules and anti-cooperative host-multi-guest chemistry.Chemical science · 2024Article
- Programmable synthesis of organic cages with reduced symmetry.Chemical science · 2024Article
- Diastereoselective Self-Assembly of Low-Symmetry PdAngewandte Chemie (International ed. in English) · 2023Article
- Modular enhancement of circularly polarized luminescence in PdChemical communications (Cambridge, England) · 2023Article
Corrections and comments
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Authors and funding
1 author.
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Abstract
Heteroleptic metal-organic cages, formed through integrative self-assembly of ligand mixtures, are highly attractive as reduced symmetry supramolecular hosts. Ensuring high-fidelity, non-statistical self-assembly, however, presents a significant challenge in molecular engineering due to the inherent difficulty in predicting thermodynamic energy landscapes. In this work, two conceptual strategies are described that circumvent this issue, using ligand design strategies to access structurally sophisticated metal-organic hosts. Using these approaches, it was possible to realise cavity environments described by two inequivalent, unsymmetrical ligand frameworks, representing a significant step forward in the construction of highly anisotropic confined spaces.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.