Evidence map›Paper›PMID 36070397›Full record

ReviewChemical reviews2022

Single-Atom Catalysis: Insights from Model Systems.

Florian Kraushofer, Gareth S Parkinson

Abstract readReview
In one paragraph

Review in Chemical reviews, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.

0numbers the graph read from it
0cells of the map it votes in
17citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

17 citing papers in PubMed.

  1. Article
  2. Article
  3. Review
  4. Review
  5. Hydrogen Activation via Dihydride Formation on a RhAngewandte Chemie (International ed. in English) · 2026
    Article
  6. Article
  7. Article
  8. Article
  9. Review
  10. Ambient pressure XPS at MAX IV.Beilstein journal of nanotechnology · 2025
    Review
  11. Article
  12. A Multitechnique Study of CThe journal of physical chemistry. C, Nanomaterials and interfaces · 2024
    Article
  13. Article
  14. Reduction of (100)-Faceted CeOChemistry of materials : a publication of the American Chemical Society · 2024
    Article
  15. Article
  16. The Role ofChemical reviews · 2023
    Review
  17. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

2 authors.

Florian KraushoferInstitute of Applied Physics, Technische Universitat Wien, 1040 Vienna, Austria.ORCID 0000-0003-1314-9149
Gareth S ParkinsonInstitute of Applied Physics, Technische Universitat Wien, 1040 Vienna, Austria.ORCID 0000-0003-2457-8977

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The field of single-atom catalysis (SAC) has expanded greatly in recent years. While there has been much success developing new synthesis methods, a fundamental disconnect exists between most experiments and the theoretical computations used to model them. The real catalysts are based on powder supports, which inevitably contain a multitude of different facets, different surface sites, defects, hydroxyl groups, and other contaminants due to the environment. This makes it extremely difficult to determine the structure of the active SAC site using current techniques. To be tractable, computations aimed at modeling SAC utilize periodic boundary conditions and low-index facets of an idealized support. Thus, the reaction barriers and mechanisms determined computationally represent, at best, a plausibility argument, and there is a strong chance that some critical aspect is omitted. One way to better understand what is plausible is by experimental modeling, i.e., comparing the results of computations to experiments based on precisely defined single-crystalline supports prepared in an ultrahigh-vacuum (UHV) environment. In this review, we report the status of the surface-science literature as it pertains to SAC. We focus on experimental work on supports where the site of the metal atom are unambiguously determined from experiment, in particular, the surfaces of rutile and anatase TiO

Identifiers

PMID36070397
PMCPMC9523716

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.