ArticleNature communications2022
Rhodium nanocrystals on porous graphdiyne for electrocatalytic hydrogen evolution from saline water.
Article in Nature communications, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 29 papers.
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Who cites it
29 citing papers in PubMed.
- From Atomic-Scale Engineering to Industry-Ready Systems: Prospects for Seawater Electrolysis Toward Hydrogen.Small (Weinheim an der Bergstrasse, Germany) · 2026Review
- Rational Design and Synthesis of a Nanostructured Electrochemical Reactor for Alkaline Hydrogen Evolution Reaction Electrode.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Controlled Lattice Distortion and Lattice-Strain-Engineered CoCuIr Alloy toward Preferential Chlorine Tolerant Direct Seawater Electrolysis.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Rhodium Single-Atom Decorated CeOSmall (Weinheim an der Bergstrasse, Germany) · 2026Article
- A Surface Engineering Strategy to Suppress Cathodic Precipitation in Seawater Electrolysis.Small science · 2026Article
- Graphdiyne-Stabilized Cobalt Oxyhydroxide Quantum Dots for Efficient Nitrate-to-Ammonia Electrocatalysis.ChemSusChem · 2026Article
- Metal Atoms and Quantum Dots Coexist for Water Electrolysis.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Rational design of interfacial sp C─S─Zn hybridization in ZnS/graphdiyne for mercury vapor capture.Science advances · 2026Article
- Stacked-overlapped graphdiyne nano-iontronics enabling enhanced monovalent/divalent cation selectivity for single-cell pH detection.National science review · 2026Article
- High-spin transition metal atoms drive acidic oxygen evolution reactions.Nature communications · 2026Article
- Pyrolysis-Free Formed Cooperative Coupling Pt-Co Dual-Functional Sites for Saline Electrolysis with High Adaptability.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Boron-Insertion-Induced Lattice Engineering of Rh Nanocrystals Toward Enhanced Electrocatalytic Conversion of Nitric Oxide to Ammonia.Nano-micro letters · 2025Article
- Highly selective aldehyde coupling on the heterointerface of molybdenum selenide and graphdiyne.Science advances · 2025Article
- Engineered PWNature communications · 2025Article
- Water and seawater splitting with MgBScientific reports · 2025Article
- The Alkynyl π Bond of sp-C Enhanced Rapid, Reversible Li-C Coupling to Accelerate Reaction Kinetics of Lithium Ions.Journal of the American Chemical Society · 2024Article
- Growing highly ordered Pt and Mn bimetallic single atomic layers over graphdiyne.Nature communications · 2024Article
- Direct conversion of CONational science review · 2024Article
- Controlled Synthesis of Graphdiyne-Based Multiscale Catalysts for Energy Conversion.Precision chemistry · 2024Review
- Flexible tungsten disulfide superstructure engineering for efficient alkaline hydrogen evolution in anion exchange membrane water electrolysers.Nature communications · 2024Article
Corrections and comments
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Authors and funding
7 authors.
Funding
Abstract
The realization of the efficient hydrogen conversion with large current densities at low overpotentials represents the development trend of this field. Here we report the atomic active sites tailoring through a facile synthetic method to yield well-defined Rhodium nanocrystals in aqueous solution using formic acid as the reducing agent and graphdiyne as the stabilizing support. High-resolution high-angle annular dark-field scanning-transmission electron microscopy images show the high-density atomic steps on the faces of hexahedral Rh nanocrystals. Experimental results reveal the formation of stable sp-C~Rh bonds can stabilize Rh nanocrystals and further improve charge transfer ability in the system. Experimental and density functional theory calculation results solidly demonstrate the exposed high active stepped surfaces and various metal atomic sites affect the electronic structure of the catalyst to reduce the overpotential resulting in the large-current hydrogen production from saline water. This exciting result demonstrates unmatched electrocatalytic performance and highly stable saline water electrolysis.
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Registered trials
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