ArticleNature communications2022
Controllable synthesis of conjugated microporous polymer films for ultrasensitive detection of chemical warfare agents.
Article in Nature communications, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
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Who cites it
9 citing papers in PubMed.
- Polymers for Detecting or Protecting Against Chemical Warfare Agents: Recent Advances and Future Perspectives.Polymers · 2026Review
- Natural Sunlight-Driven Synthesis of Conjugated Microporous Polymers via Electron Donor-Acceptor Complexes for Highly Efficient Catalytic Upcycling of Real-World Plastic Waste.Angewandte Chemie (International ed. in English) · 2026Article
- Three in one fluorescent sensing and imaging of chemical warfare agents.Nature communications · 2026Article
- Recent Advances in Conjugated Microporous Polymers for Photocatalysis: Mechanism, Synthesis and Applications.Exploration (Beijing, China) · 2026Review
- Article
- Article
- Interfacial engineered superelastic metal-organic framework aerogels with van-der-Waals barrier channels for nerve agents decomposition.Nature communications · 2023Article
- A Turn-On and Colorimetric Probe Based on Isophorone Skeleton for Detecting Nerve Agent Mimic Diethyl Chlorophosphite.Molecules (Basel, Switzerland) · 2023Article
- Synthesis and Characterization of MnOMaterials (Basel, Switzerland) · 2022Article
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Authors and funding
9 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Nerve agents, one of the most toxic chemical warfare agents, seriously threaten human life and public security. The high toxicity of nerve agents makes the development of fluorescence sensors with suitable limit of detection challenging. Here, we propose a sensor design based on a conjugated microporous polymer film for the detection of diethyl chlorophosphate, a substitute of Sarin, with low detection limit of 2.5 ppt. This is due to the synergy of the susceptible on-off effect of hybridization and de-hybridization of hybrid local and charge transfer (HLCT) materials and the microporous structure of CMP films facilitating the inward diffusion of DCP vapors, and the extended π-conjugated structure. This strategy provides a new idea for the future development of gas sensors. In addition, a portable sensor is successfully integrated based on TCzP-CMP films that enables wireless, remote, ultrasensitive, and real-time detection of DCP vapors.
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