ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2022
Spatially Confined Face-Selective Growth of Large-Area 2D Organic Molecular Crystals in a Supramolecular Gel for Highly Efficient Flexible Photodetection.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Solution-Processed Monolayer Molecular Crystals: From Precise Preparation to Advanced Applications.Precision chemistry · 2024Review
- Recent advances in supramolecular fullerene chemistry.Chemical Society reviews · 2024Review
- Spatially Confined Face-Selective Growth of Large-Area 2D Organic Molecular Crystals in a Supramolecular Gel for Highly Efficient Flexible Photodetection.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2022Article
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11 authors.
Funding
Abstract
2D organic molecular crystals (2DOMCs) are promising materials for the fabrication of high-performance optoelectronic devices. However, the growth of organic molecules into 2DOMCs remains a challenge because of the difficulties in controlling their self-assembly with a preferential orientation in solution-process crystallization. Herein, fullerene is chosen as a model molecule to develop a supramolecular gel crystallization approach to grow large-area 2DOMCs by controlling the perfect arrangement on the {220} crystal plane with the assistance of a gelated solvent. In this case, the gel networks provide tuneable confined spaces to control the crystallization kinetics toward the growth of dominant crystal faces by their inhibiting motions of solvent or solute molecules to enable the growth of perfect crystals at appropriate nucleation rates. As a result, a large-area fullerene 2DOMC is produced successfully and its corresponding device on a flexible substrate exhibits excellent bendable properties and ultra-high weak light detection ability (2.9 × 10
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