ArticleJournal of the American Chemical Society2022
Covalent Adsorption of N-Heterocyclic Carbenes on a Copper Oxide Surface.
Article in Journal of the American Chemical Society, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
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Who cites it
16 citing papers in PubMed.
- N-Heterocyclic carbenes on copper: a dynamic and sensitive interplay between surface functionalization and etching.Chemical science · 2026Article
- Ultra-Thin and Highly Insulating Aromatic Monolayers by N-Heterocyclic Carbenes.Angewandte Chemie (International ed. in English) · 2026Article
- Out of the Crystalline Comfort Zone: Sampling the Initial Oxide Formation At Cu(111).Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- N-Heterocyclic Carbenes on a III-V Semiconductor: From Chain Formation to Ordered Monolayers.Angewandte Chemie (International ed. in English) · 2025Article
- Article
- Surface Characterization of N-Heterocyclic Carbenes on Gold and Silver: Exploring Distinct Crystalline Facets.Chemphyschem : a European journal of chemical physics and physical chemistry · 2025Article
- Writing with Molecules: Tip-Induced Local Chemisorption of N-Heterocyclic Olefins on Cu(111).Journal of the American Chemical Society · 2025Article
- Density Functional Theory Investigation of Simple N-Heterocyclic Carbenes Adsorbed on the Pd/Cu(111) Single-Atom Alloy Surface.ACS omega · 2025Article
- Self-Assembled Monolayer of N-Heterocyclic Carbene as a Primer in a Dual-Layer Coating for Corrosion Protection on Iron.Angewandte Chemie (International ed. in English) · 2025Article
- Odd-Even Effects in the Structure and Thermal Stability of Carboxylic Acid Anchored Monolayers on Naturally Oxidized Aluminum Surface.The journal of physical chemistry letters · 2025Article
- N-Heterocyclic Carbene Monolayers on Metal-Oxide Films: Correlations between Adsorption Mode and Surface Functionality.Langmuir : the ACS journal of surfaces and colloids · 2024Article
- Enhanced catalytic activity of N-heterocyclic carbene stabilized surface adatoms for CO reduction reaction.Communications chemistry · 2023Article
- Article
- NHC stabilized copper nanoparticlesChemical communications (Cambridge, England) · 2023Article
- Stability of N-Heterocyclic Carbene Monolayers under Continuous Voltammetric Interrogation.ACS applied materials & interfaces · 2023Article
- N-Heterocyclic Carbenes: Molecular Porters of Surface Mounted Ru-Porphyrins.Angewandte Chemie (International ed. in English) · 2022Article
Corrections and comments
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Authors and funding
9 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Tuning the properties of oxide surfaces through the adsorption of designed ligands is highly desirable for several applications, such as catalysis. N-Heterocyclic carbenes (NHCs) have been successfully employed as ligands for the modification of metallic surfaces. On the other hand, their potential as modifiers of ubiquitous oxide surfaces still needs to be developed. Here we show that a model NHC binds covalently to a copper oxide surface under UHV conditions. In particular, we report the first example of a covalent bond between NHCs and oxygen atoms from the oxide layer. This study demonstrates that NHC can also act as a strong anchor on oxide surfaces.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.