ArticleThe journal of physical chemistry letters2022
Vibrational Polaritons in Disordered Molecular Ensembles.
Article in The journal of physical chemistry letters, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
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Who cites it
9 citing papers in PubMed.
- Quantifying the Number of Dark, Gray, and Bright States as a Function of the Spectral Overlap in Polaritonic Systems.Nano letters · 2026Article
- Interference-Induced Cavity Resonances and Imaginary Rabi Splitting.Nanophotonics (Berlin, Germany) · 2026Article
- Phase-Resolved Two-Dimensional Infrared Spectroscopy of Solution-Phase Vibrational Polaritons on Gold Antenna Meta-Surfaces.The journal of physical chemistry letters · 2026Article
- Vibrational weak and strong coupling modify a chemical reaction via cavity-mediated radiative energy transfer.Nature chemistry · 2025Article
- Probing the anharmonicity of vibrational polaritons with double-quantum two-dimensional infrared spectroscopy.Nanophotonics (Berlin, Germany) · 2024Article
- Extracting accurate light-matter couplings from disordered polaritons.Nanophotonics (Berlin, Germany) · 2024Article
- The role of dephasing for dark state coupling in a molecular Tavis-Cummings model.The Journal of chemical physics · 2023Article
- Chiral Polaritonics: Analytical Solutions, Intuition, and Use.The journal of physical chemistry letters · 2023Article
- Simulating molecular polaritons in the collective regime using few-molecule models.Proceedings of the National Academy of Sciences of the United States of America · 2023Article
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4 authors.
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Abstract
Disorder is an intrinsic attribute of any realistic molecular system. It is known to lead to localization, which hampers efficient transport. It was recently proposed that in molecular ensembles strongly coupled to photonic cavities, moderate disorder leads to delocalization and increases of the transport and chemical reaction rates. Vibrational polaritons involve molecular vibrations hybridized with an infrared cavity. When the coupling strength largely exceeds the molecular inhomogeneity, polaritons are unaffected by disorder. However, in many experiments, such a homogeneous limit does not apply. We investigated vibrational polaritons involving molecular ensembles with systematically modified disorder. Counterintuitively, moderate disorder leads to an increase in Rabi splitting and the modification of the polariton bandwidths. Experimental spectroscopic data agree with a Tavis-Cummings-like model that suggests enhanced delocalization of the reservoir states occurs via the admixture of the cavity mode. Our results provide new insights into the paradigm of disorder-induced cavity-assisted delocalization in molecular polaritons.
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