ArticleAngewandte Chemie (International ed. in English)2022
Heterocyclic Hemithioindigos: Highly Advantageous Properties as Molecular Photoswitches.
Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 28 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
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Who cites it
28 citing papers in PubMed.
- Dynamic Control of Nucleic Acids Self-Assembly and Expression Using Photoswitches.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Review
- Photochromism of Dicyanorhodanine-Pyrrole Conjugates: Substituent and Solvent Effects.ACS omega · 2026Article
- Chalcogen substitution co-tunes photochromism and hydrogen bonding in semicarbazone photoswitches.Chemical science · 2026Article
- A Reversible 900 nm Near-Infrared Photoswitch for Invisibly Writable 2D and 3D Displays.Angewandte Chemie (International ed. in English) · 2026Article
- A supercharged molecular motor operating by constitutional alteration and proton transfer.Nature chemistry · 2026Article
- Thermally Bistable Stiff Stilbene Photoswitches and Polymer Applications.Chemical record (New York, N.Y.) · 2026Article
- Acid- and Nucleophile-Gated Photoisomerization of Phosphaindirubin.Angewandte Chemie (International ed. in English) · 2026Article
- The Heterocycle Isostere Explorer: A Computational Tool for the Discovery of Novel Aromatic Heterocyclic Isosteres.Journal of medicinal chemistry · 2026Article
- Heteroaryl iminothioindoxyl (HA-ITI) photoswitchesChemical science · 2026Article
- Visible-light-triggered exclusive bistable E/Z photoswitching based on sterically frustrated dicyanostilbene derivatives.Nature communications · 2026Article
- Hemi-Indigiosin: A pH and Red-Light Responsive Transmembrane HCl Transporter.Angewandte Chemie (International ed. in English) · 2025Article
- Arylpyrrolylidene-indanones as readily synthesised photoswitches offering dual- and single-colour fluorescence toggling with nearly quantitativeChemical science · 2025Article
- Complex Multistate Photophysics of a Rhodanine Photoswitch.Angewandte Chemie (International ed. in English) · 2025Article
- The Effect of Aldehyde and Carboxylic Acid Substitution on the Isomerization of Hemithioindigo Photoswitches.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Azobenzene-Oxindole Photochromic Dyads.Angewandte Chemie (International ed. in English) · 2025Article
- Synthesis and Evaluation of the Photochemical Properties of Heterocyclic Hemiindigos.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Hemiphosphoindigos as a platform for chiroptical or water soluble photoswitching.Nature communications · 2025Article
- Thiosemicarbazones as versatile photoswitches with light-controllable supramolecular activity.Chemical science · 2025Article
- Switching Sides: Regiochemistry and Functionalization Dictate the Photoswitching Properties of Imines.Angewandte Chemie (International ed. in English) · 2025Article
- Combined Photopolymerization and Localized Photochromism by Aza-Diarylethene and Hemiindigo Synergy.Advanced materials (Deerfield Beach, Fla.) · 2025Article
Corrections and comments
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Authors and funding
3 authors.
Funding
Abstract
A survey of heterocyclic hemithioindigo photoswitches is presented identifying a number of structural motives with outstanding property profiles. The highly sought-after combination of pronounced color change, quantitative switching in both directions, exceptional high quantum yields, and tunable high thermal stability of metastable states can be realized with 4-imidazole, 2-pyrrole, and 3-indole-based derivatives. In the former, an unusual preorganization using isomer selective chalcogen- and hydrogen bonding allows to precisely control geometry changes and tautomerism upon switching. Heterocyclic hemithioindigos thus represent highly promising photoswitches with advanced capabilities that will be of great value to anyone interested in establishing defined and reversible control at the molecular level.
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Registered trials
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