A ligand-enabled metallaphotoredox protocol for Suzuki-Miyaura cross-couplings for the synthesis of diarylmethanes.

Jianbin Li, Chia-Yu Huang, Chao-Jun Li

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Article in STAR protocols, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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3 authors.

Jianbin LiDepartment of Chemistry, FRQNT Centre for Green Chemistry and Catalysis, McGill University, 801 Sherbrooke Street W., Montreal, QC H3A 0B8, Canada.

Chia-Yu HuangDepartment of Chemistry, FRQNT Centre for Green Chemistry and Catalysis, McGill University, 801 Sherbrooke Street W., Montreal, QC H3A 0B8, Canada.

Chao-Jun LiDepartment of Chemistry, FRQNT Centre for Green Chemistry and Catalysis, McGill University, 801 Sherbrooke Street W., Montreal, QC H3A 0B8, Canada. Electronic address: cj.li@mcgill.ca.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Here, we present a ligand-enabled metallaphotoredox Suzuki-Miyaura cross-coupling protocol for the facile synthesis of diarylmethanes. Specifically, we describe the preparation of a unique class of ligands, 2,4-diarylquinolines, and demonstrate their application in nickel-catalyzed fragment couplings between alkyltrifluoroborates and haloarenes. We detail the synthesis of the most enabling ligand, PPQN

Indexed as

NickelCatalysisLigandsLigandsNickelChemistryEnergy

Identifiers

PMID36035803

DOI10.1016/j.xpro.2022.101618

PMCPMC9405098

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