ArticleACS catalysis2022
Cobalt-Catalyzed Hydrogenation Reactions Enabled by Ligand-Based Storage of Dihydrogen.
Article in ACS catalysis, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
6 citing papers in PubMed.
- Electrochemical reduction of unsaturated carbon-carbon bonds via 3d transition-metal catalysis.Beilstein journal of organic chemistry · 2026Review
- Metal-ligand cooperativity in chemical electrosynthesis.Chem catalysis · 2024Article
- Selective Cobalt-Mediated Formation of Hydrogen Peroxide from Water under Mild Conditions via Ligand Redox Non-Innocence.Journal of the American Chemical Society · 2024Article
- Hydrogenation of Terminal Alkenes Catalyzed by Air-Stable Mn(I) Complexes Bearing an N-Heterocyclic Carbene-Based PCP Pincer Ligand.Chemistry (Weinheim an der Bergstrasse, Germany) · 2024Article
- Electrocatalytic Semihydrogenation of Terminal Alkynes Using Ligand-Based Transfer of Protons and Electrons.Journal of the American Chemical Society · 2024Article
- Hydride-Free Hydrogenation: Unraveling the Mechanism of Electrocatalytic Alkyne Semihydrogenation by Nickel-Bipyridine Complexes.Journal of the American Chemical Society · 2023Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
3 authors.
Funding
Abstract
The use of supporting ligands that can store either protons or electrons has emerged as a powerful strategy in catalysis. While these strategies are potent individually, natural systems mediate remarkable transformations by combining the storage of both protons and electrons in the secondary coordination sphere. As such, there has been recent interest in using this strategy to enable fundamentally different transformations. Furthermore, outsourcing H-atom or hydrogen storage to ancillary ligands can also enable alternative mechanistic pathways and thereby selectivity. Here, we describe the application of this strategy to facilitate radical reactivity in Co-based hydrogenation catalysis. Metalation of previously reported dihydrazonopyrrole ligands with Co results in paramagnetic complexes, which are best described as having Co(II) oxidation states. These complexes catalytically hydrogenate olefins with low catalyst loadings under mild conditions (1 atm H
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.