ArticleChemistry of materials : a publication of the American Chemical Society2022
Ion-Pairs in Aluminosilicate-Alkali Synthesis Liquids Determine the Aluminum Content and Topology of Crystallizing Zeolites.
Article in Chemistry of materials : a publication of the American Chemical Society, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
11 citing papers in PubMed.
- Ion exchange selectivity governs phase selection in zeolite synthesis.Materials horizons · 2025Article
- Split Syntheses: Introducing Bottom-Up Control over Aluminum in SSZ-13 and ZSM-5 Zeolites.JACS Au · 2025Article
- Multifunctional Catalysts for Cascade Reactions in Biomass Processing.Nanomaterials (Basel, Switzerland) · 2024Review
- Highly efficient synthesis of zeolite chabazite using cooperative hydration-mismatched inorganic structure-directing agents.Chemical science · 2024Article
- Cation-induced speciation of port-size during mordenite zeolite synthesis.Journal of materials chemistry. A · 2023Article
- Illuminating the Black Box: A Perspective on Zeolite Crystallization in Inorganic Media.Accounts of chemical research · 2023Article
- Does Water Enable Porosity in Aluminosilicate Zeolites? Porous Frameworks versus Dense Minerals.Crystal growth & design · 2023Article
- Regulation of the Si/Al ratios and Al distributions of zeolites and their impact on properties.Chemical science · 2023Review
- Structural Aspects Affecting Phase Selection in Inorganic Zeolite Synthesis.Chemistry of materials : a publication of the American Chemical Society · 2022Article
- HSIL-Based Synthesis of Ultracrystalline K,Na-JBW, a Zeolite Exhibiting Exceptional Framework Ordering and Flexibility.Chemistry of materials : a publication of the American Chemical Society · 2022Article
- Nucleation of Porous Crystals from Ion-Paired Prenucleation Clusters.Chemistry of materials : a publication of the American Chemical Society · 2022Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
9 authors.
Funding
Abstract
Using hydrated silicate ionic liquids, phase selection and framework silicon-to-aluminum ratio during inorganic zeolite synthesis were studied as a function of batch composition. Consisting of homogeneous single phasic liquids, this synthesis concept allows careful control of crystallization parameters and evaluation of yield and sample homogeneity. Ternary phase diagrams were constructed for syntheses at 90 °C for 1 week. The results reveal a cation-dependent continuous relation between batch stoichiometry and framework aluminum content, valid across the phase boundaries of all different zeolites formed in the system. The framework aluminum content directly correlates to the type of alkali cation and gradually changes with batch alkalinity and dilution. This suggests that the observed zeolites form through a solution-mediated mechanism involving the concerted assembly of soluble cation-oligomer ion pairs. Phase selection is a consequence of the stability for a particular framework at the given aluminum content and alkali type.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.