ArticleChemistry of materials : a publication of the American Chemical Society2022
Excited-State Lifetime Modulation by Twisted and Tilted Molecular Design in Carbene-Metal-Amide Photoemitters.
Article in Chemistry of materials : a publication of the American Chemical Society, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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Who cites it
8 citing papers in PubMed.
- Au(I) Complex With an Abnormal Carbene Ligand Shows Anti-Kasha Dual Photoluminescence Emission.Angewandte Chemie (International ed. in English) · 2026Article
- Substituent-controlled donor binding and local reactivity in N-heterocyclic carbene copper amide complexes: a DFT study.Journal of molecular modeling · 2026Article
- Carbene-Metal-Amide Materials Design: Tailoring π-Extended Amides for High-Performance Organic Light-Emitting Diodes.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Recent advances in mono- and multi-nuclear photoluminescent Cu(i) complexes with nitrogen containing ligands and their stimuli responsiveness.Chemical science · 2025Review
- A comprehensive DFT/TDDFT investigation into the influence of electron acceptors on the photophysical properties of ullazine-based D-π-A-π-A photosensitizers.Scientific reports · 2025Article
- Luminescent carbene-copper(i)-amide polymers for efficient host-free solution-processed OLEDs.Chemical science · 2024Article
- The Equilibrium Molecular Structure of Cyclic (Alkyl)(Amino) Carbene Copper(I) Chloride via Gas-Phase Electron Diffraction and Quantum Chemical Calculations.Molecules (Basel, Switzerland) · 2023Article
- Organic persistent room temperature phosphorescence enabled by carbazole impurity.Frontiers in chemistry · 2022Article
Corrections and comments
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Authors and funding
10 authors.
Funding
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Abstract
Carbene-metal-amides (CMAs) are an emerging class of photoemitters based on a linear donor-linker-acceptor arrangement. They exhibit high flexibility about the carbene-metal and metal-amide bonds, leading to a conformational freedom which has a strong influence on their photophysical properties. Herein we report CMA complexes with (1) nearly coplanar, (2) twisted, (3) tilted, and (4) tilt-twisted orientations between donor and acceptor ligands and illustrate the influence of preferred ground-state conformations on both the luminescence quantum yields and excited-state lifetimes. The performance is found to be optimum for structures with partially twisted and/or tilted conformations, resulting in radiative rates exceeding 1 × 10
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Registered trials
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