ReviewJACS Au2022
Double Gyroid Morphologies in Precise Ion-Containing Multiblock Copolymers Synthesized via Step-Growth Polymerization.
Review in JACS Au, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
7 citing papers in PubMed.
- Advances in Cubosome-Based Transdermal Delivery: Structural Design, Manufacturing, and Engineering Strategies.ACS omega · 2026Review
- Solid-State Ion-Conducting Multiblock Terpolymers.Macromolecules · 2026Review
- Architecture Effect on Network Phase Formation from Controlled Self-Assembly of High‑χ Block Copolymers.Macromolecules · 2025Article
- Polymerization-induced self-assembly enables access to diverse highly ordered structures through kinetic and thermodynamic pathways.Chemical science · 2025Article
- Polymer design for solid-state batteries and wearable electronics.Chemical science · 2024Review
- Self-Assembled Block Copolymers as a Facile Pathway to Create Functional Nanobiosensor and Nanobiomaterial Surfaces.Polymers · 2024Review
- Design of Microstructure-Engineered Polymers for Energy and Environmental Conservation.JACS Au · 2023Review
Corrections and comments
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Authors and funding
2 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The double gyroid structure was first reported in diblock copolymers about 30 years ago, and the complexity of this morphology relative to the other ordered morphologies in block copolymers continues to fascinate the soft matter community. The double gyroid microphase-separated morphology has co-continuous domains of both species, and the minority phase is subdivided into two interpenetrating network structures. In addition to diblock copolymers, this structure has been reported in similar systems including diblock copolymers blended with one or two homopolymers and ABA-type triblock copolymers. Given the narrow composition region over which the double gyroid structure is typically observed (∼3 vol %), anionic polymerization has dominated the synthesis of block copolymers to control their composition and molecular weight. This perspective will highlight recent studies that (1) employ an alternative polymerization method to make block copolymers and (2) report double gyroid structures with lattice parameters below 10 nm. Specifically, step-growth polymerization linked precise polyethylene blocks and short sulfonate-containing blocks to form strictly alternating multiblock copolymers, and these copolymers produce the double gyroid structure over a dramatically wider composition range (>14 vol %). These new (AB)
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Registered trials
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