Evidence map›Paper›PMID 36017770›Full record

ArticleAngewandte Chemie (International ed. in English)2022

Light-Driven Hydrodefluorination of Electron-Rich Aryl Fluorides by an Anionic Rhodium-Gallium Photoredox Catalyst.

James T Moore, Michael J Dorantes, Zihan Pengmei, Timothy M Schwartz, Jacob Schaffner, Samantha L Apps, Carlo A Gaggioli, Ujjal Das, Laura Gagliardi, David A Blank and 1 more

Open access · hybridAbstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
2.2field-weighted citation impact, top 12% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed, 29 citations in OpenAlex.

  1. Review
  2. Article
  3. Article
  4. Review
  5. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors at 3 institutions in 2 countries.

James T MooreDepartment of Chemistry, University of Minnesota, 207 Pleasant Street SE, Minneapolis, Minnesota, 55455-0431, USA.
Michael J DorantesDepartment of Chemistry, University of Minnesota, 207 Pleasant Street SE, Minneapolis, Minnesota, 55455-0431, USA.ORCID http://orcid.org/0000-0002-8220-911X
Zihan PengmeiDepartment of Chemistry, University of Minnesota, 207 Pleasant Street SE, Minneapolis, Minnesota, 55455-0431, USA.
Timothy M SchwartzDepartment of Chemistry, University of Minnesota, 207 Pleasant Street SE, Minneapolis, Minnesota, 55455-0431, USA.ORCID http://orcid.org/0000-0002-9070-6810
Jacob SchaffnerDepartment of Chemistry, University of Minnesota, 207 Pleasant Street SE, Minneapolis, Minnesota, 55455-0431, USA.
Samantha L AppsDepartment of Chemistry, University of Minnesota, 207 Pleasant Street SE, Minneapolis, Minnesota, 55455-0431, USA.
Carlo A GaggioliDepartment of Chemistry, University of Chicago, 5735 S Ellis Ave., Chicago, Illinois, 60637, USA.
Ujjal DasInstitut für Anorganische Chemie, Universität Bonn, Gerhard-Domagk-Str. 1, Bonn, 53121, Deutschland.ORCID http://orcid.org/0000-0002-1895-5767
Laura GagliardiDepartment of Chemistry, University of Chicago, 5735 S Ellis Ave., Chicago, Illinois, 60637, USA.ORCID http://orcid.org/0000-0001-5227-1396
David A BlankDepartment of Chemistry, University of Minnesota, 207 Pleasant Street SE, Minneapolis, Minnesota, 55455-0431, USA.
Connie C LuDepartment of Chemistry, University of Minnesota, 207 Pleasant Street SE, Minneapolis, Minnesota, 55455-0431, USA.ORCID http://orcid.org/0000-0002-5162-9250
University of Minnesota · USUniversity of Chicago · USUniversity of Bonn · DE

Funding

National Science Foundation 2102095, 2054723
6 · The paper itself

Abstract

An anionic Rh-Ga complex catalyzed the hydrodefluorination of challenging C-F bonds in electron-rich aryl fluorides and trifluoromethylarenes when irradiated with violet light in the presence of H

Indexed as

GalliumHeterobimetallicHydrodefluorinationPhotoredox CatalysisRhodium

Identifiers

PMID36017770
PMCPMC9826370
OpenAlexW4293194550

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC-ND
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.