ArticlePolymers2022
Increase the Surface PANI Occupancy of Electrospun PMMA/PANI Fibers: Effect of the Electrospinning Parameters on Surface Segregation.
Article in Polymers, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
1 citing paper in PubMed.
- Comprehensive Investigation of the Commercial ELP-20 Electron-Beam Lithography Resist.Micromachines · 2025Article
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Authors and funding
5 authors.
Funding
Abstract
For preparing high-performance electrospun fibers with functional molecules that cannot cross-entangle themselves, such as conductive polymers, promoting the aggregation of functional molecules on the surface by surface segregation is a promising approach. In the present study, electrospun polymethyl methacrylate/polyaniline (PMMA/PANI) fibers were prepared under various conditions, including solution composition, applied voltage, tip-to-collector distance, temperature, humidity, and gas-phase solvent concentration, to examine the effects of the parameters on fiber morphology and surface segregation. The changes in fiber morphology and variations in the intensity of PANI and PMMA's characteristic bands were investigated with scanning electron microscopy (SEM) and Raman spectroscopy. The results demonstrated that by changing the saturation difference and the viscosity, the amount of PMMA and PANI added significantly influenced whether surface segregation could occur. The effect of other investigated parameters on surface segregation was concluded to alter the molecular migratable time by affecting the jet flight time and the solvent volatilization rate. Among them, increasing the solvent concentration could significantly promote surface segregation without sacrificing morphological advantages. When the solvent concentration increased from 1.4 to 158 mg/m
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