Evidence map›Paper›PMID 36014420›Full record

ArticleMolecules (Basel, Switzerland)2022

Thermodynamic vs. Kinetic Control in Synthesis of

Anton A Muravev, Alexander S Ovsyannikov, Gennady V Konorov, Daut R Islamov, Konstantin S Usachev, Alexander S Novikov, Svetlana E Solovieva, Igor S Antipin

Open access · goldAbstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Molecules (Basel, Switzerland), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
0.7field-weighted citation impact, top 37% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed, 6 citations in OpenAlex.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors at 4 institutions in 1 country.

Anton A MuravevInfochemistry Scientific Center, ITMO University, 191002 St.-Petersburg, Russia.ORCID 0000-0002-2245-3460
Alexander S OvsyannikovArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, 420008 Kazan, Russia.ORCID 0000-0002-5941-844X
Gennady V KonorovButlerov Institute of Chemistry, Kazan Federal University, 420008 Kazan, Russia.
Daut R IslamovArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, 420008 Kazan, Russia.
Konstantin S UsachevInstitute of Fundamental Medicine and Biology, Kazan Federal University, 420008 Kazan, Russia.ORCID 0000-0002-6331-7764
Alexander S NovikovInstitute of Chemistry, St.-Petersburg State University, 199034 St.-Petersburg, Russia.ORCID 0000-0001-9913-5324
Svetlana E SolovievaArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, 420008 Kazan, Russia.
Igor S AntipinArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, 420008 Kazan, Russia.
A.E. Arbuzov Institute of Organic and Physical Chemistry · RUKazan Federal University · RUITMO University · RUPeoples' Friendship University of Russia · RU

Funding

RUDN University Strategic Academic Leadership ProgramRussian Science Foundation 21-73-10185State Assignment for Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences 122011800132-5
6 · The paper itself

Abstract

Elaboration of a convenient route towards donor-substituted pyrazoles from heteropropargyl precursors is challenging due to a number of thermodynamically favorable side reactions (e.g., acetylene-allene isomerization and Glaser homocoupling). In this work, Sonogashira cross-coupling conditions of 4-

Indexed as

FuransPyrazolesSolventsThermodynamicsFuranspyrazolePyrazolesSolvents2,5-substituted furansDFT calculationsdonor-substituted pyrazolesprototropic tautomerismSonogashira cross-couplingtandem Michael addition/cyclocondensation

Identifiers

PMID36014420
PMCPMC9413326
OpenAlexW4291512478

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.