ArticleOrganic letters2022
Solvent Anions Enable Photoinduced Borylation and Phosphonation of Aryl Halides via EDA Complexes.
Article in Organic letters, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
What it found
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Who cites it
13 citing papers in PubMed, 49 citations in OpenAlex.
- Visible-Light-Induced Carbon-Hydrogen Phosphonylation of Conjugated Polymers via Electron Donor-Acceptor Complex Activation.Angewandte Chemie (International ed. in English) · 2026Article
- Deprotection of benzyl ethersGreen chemistry : an international journal and green chemistry resource : GC · 2026Article
- Achieving Diverse Functionalizations of Electron-Deficient Aryl Halides via Carbonate-Mediated Electron-Donor-Acceptor Complexes.European journal of organic chemistry · 2026Article
- Generation of a Ground-State Electron Donor Utilizing Stored Light Energy.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- EDA Complex-Mediated C(spEuropean journal of organic chemistry · 2026Article
- Photocatalytic Aminoarylation of Styrenes.Organic letters · 2026Article
- A Diverse Array of Catalytic Photoredox Reactions Based on Aluminum(III)-Salen Complexes: Understanding the Enhancement of Catalytic Activity via Amine Association.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Sequential EDA/HAT Enables C(spOrganic letters · 2025Article
- Iodoarene Activation: Take a Leap Forward toward Green and Sustainable Transformations.Chemical reviews · 2025Review
- Article
- Light-assisted functionalization of aryl radicals towards metal-free cross-coupling.Nature reviews. Chemistry · 2025Review
- Visible Light Photoredox Catalysis in the Synthesis of Phosphonate-Substituted 1,10-Phenanthrolines.Molecules (Basel, Switzerland) · 2024Article
- Site-selective and metal-free C-H phosphonation of arenesRSC advances · 2023Article
Corrections and comments
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Authors and funding
5 authors at 1 institution in 1 country.
Funding
Abstract
We report the synthesis of aryl boronic esters and aryl phosphonate esters promoted by visible-light in the absence of transition-metals or photoredox catalysts. The transformation proceeds at room temperature using sodium hydride, as a non-nucleophilic base, and exhibits functional group tolerance for anilines, amides, and esters. UV-vis spectroscopy, radical trapping experiments, and computational (TD-DFT) calculations suggest an electron-donor-acceptor (EDA) complex between solvent anions and aryl halides as the species responsible for this reactivity.
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What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.