ArticleJournal of the American Chemical Society2022
Reversible Homolysis of a Carbon-Carbon σ-Bond Enabled by Complexation-Induced Bond-Weakening.
Article in Journal of the American Chemical Society, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
8 citing papers in PubMed.
- Privileged Chiral Photocatalysts.Angewandte Chemie (International ed. in English) · 2025Review
- Review
- Article
- Catalyst Design for Rh-Catalyzed Arene and Alkane C-H Borylation: The NHC Affects the Induction Period, and Indenyl is Superior to Cp.Organometallics · 2024Article
- Coordination-induced O-H/N-H bond weakening by a redox non-innocent, aluminum-containing radical.Nature communications · 2024Article
- Article
- CpOrganometallics · 2023Article
- Combined Catalysis: A Powerful Strategy for Engineering Multifunctional Sustainable Lignin-Based Materials.ACS nano · 2023Review
Corrections and comments
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Authors and funding
4 authors.
Funding
Abstract
A case study of catalytic carbon-carbon σ-bond homolysis is presented. The coordination of a redox-active Lewis acid catalyst reduces the bond-dissociation free energies of adjacent carbon-carbon σ-bonds, and this complexation-induced bond-weakening is used to effect reversible carbon-carbon bond homolysis. Stereochemical isomerization of 1,2-disubstituted cyclopropanes was investigated as a model reaction with a ruthenium (III/II) redox couple adopted for bond weakening. Results from our mechanistic investigation into the stereospecificity of the isomerization reaction are consistent with selective complexation-induced carbon-carbon bond homolysis. The Δ
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Registered trials
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