Evidence map›Paper›PMID 35993775›Full record

ArticleJournal of the American Chemical Society2022

A Crystalline 1D Dynamic Covalent Polymer.

Elisabet De Bolòs, Marta Martínez-Abadía, Félix Hernández-Culebras, Alison Haymaker, Kyle Swain, Karol Strutyński, Benjamin L Weare, Javier Castells-Gil, Natalia M Padial, Carlos Martí-Gastaldo and 5 more

Abstract read
In one paragraph

Article in Journal of the American Chemical Society, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
  2. Review
  3. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

15 authors.

Elisabet De BolòsPOLYMAT, University of the Basque Country UPV/EHU, Avenida de Tolosa 72, Donostia-San Sebastián 20018, Spain.
Marta Martínez-AbadíaPOLYMAT, University of the Basque Country UPV/EHU, Avenida de Tolosa 72, Donostia-San Sebastián 20018, Spain.
Félix Hernández-CulebrasPOLYMAT, University of the Basque Country UPV/EHU, Avenida de Tolosa 72, Donostia-San Sebastián 20018, Spain.
Alison HaymakerChemical Engineering, School for Engineering of Matter, Transport, and Energy, Arizona State University, Tempe, Arizona 85287, United States.
Kyle SwainChemical Engineering, School for Engineering of Matter, Transport, and Energy, Arizona State University, Tempe, Arizona 85287, United States.
Karol StrutyńskiCICECO - Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, Aveiro 3810-193, Portugal.
Benjamin L WeareSchool of Chemistry, University of Nottingham, University Park, Nottingham NG7 2RD, United Kingdom.ORCID 0000-0003-4209-2604
Javier Castells-GilInstituto de Ciencia Molecular, Universidad de Valencia, Paterna 46980, Spain.
Natalia M PadialInstituto de Ciencia Molecular, Universidad de Valencia, Paterna 46980, Spain.
Carlos Martí-GastaldoInstituto de Ciencia Molecular, Universidad de Valencia, Paterna 46980, Spain.
Andrei N KhlobystovSchool of Chemistry, University of Nottingham, University Park, Nottingham NG7 2RD, United Kingdom.ORCID 0000-0001-7738-4098
Akinori SaekiDepartment of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita, Osaka 565-0871, Japan.ORCID 0000-0001-7429-2200
Manuel Melle-FrancoCICECO - Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, Aveiro 3810-193, Portugal.ORCID 0000-0003-1929-0477
Brent L NannengaChemical Engineering, School for Engineering of Matter, Transport, and Energy, Arizona State University, Tempe, Arizona 85287, United States.ORCID 0000-0001-6859-3429
Aurelio Mateo-AlonsoPOLYMAT, University of the Basque Country UPV/EHU, Avenida de Tolosa 72, Donostia-San Sebastián 20018, Spain.ORCID 0000-0002-5316-2594

Funding

Visualizing chemical bonding in biological macromolecules by microcrystal electron diffractionR21GM135784 · NIGMS · ARIZONA STATE UNIVERSITY-TEMPE CAMPUS · PI NANNENGA, BRENT · 2019 to 2020
$432k
NIGMS NIH HHS R21 GM135784
6 · The paper itself

Abstract

The synthesis of crystalline one-dimensional polymers provides a fundamental understanding about the structure-property relationship in polymeric materials and allows the preparation of materials with enhanced thermal, mechanical, and conducting properties. However, the synthesis of crystalline one-dimensional polymers remains a challenge because polymers tend to adopt amorphous or semicrystalline phases. Herein, we report the synthesis of a crystalline one-dimensional polymer in solution by dynamic covalent chemistry. The structure of the polymer has been unambiguously confirmed by microcrystal electron diffraction that together with charge transport studies and theoretical calculations show how the π-stacked chains of the polymer generate optimal channels for charge transport.

Identifiers

PMID35993775
PMCPMC9446889

What OpenQuestion holds

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LicenceCC BY
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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.