Evidence map›Paper›PMID 35977083›Full record

ArticleJournal of the American Chemical Society2022

Generation and Aerobic Oxidative Catalysis of a Cu(II) Superoxo Complex Supported by a Redox-Active Ligand.

Maia E Czaikowski, Andrew J McNeece, Jan-Niklas Boyn, Kate A Jesse, Sophie W Anferov, Alexander S Filatov, David A Mazziotti, John S Anderson

Abstract read
In one paragraph

Article in Journal of the American Chemical Society, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.

0numbers the graph read from it
0cells of the map it votes in
12citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

12 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. Article
  5. Review
  6. Article
  7. Article
  8. RSC advances · 2024
    Article
  9. Ligand-Copper(I) Primary OAccounts of chemical research · 2023
    Article
  10. Article
  11. Article
  12. A cobalt adduct of an N-hydroxy-piperidinium cation.Journal of coordination chemistry · 2022
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Maia E CzaikowskiDepartment of Chemistry, University of Chicago, Chicago, Illinois 60637, United States.ORCID 0000-0002-1334-8140
Andrew J McNeeceDepartment of Chemistry, University of Chicago, Chicago, Illinois 60637, United States.ORCID 0000-0001-8381-6539
Jan-Niklas BoynDepartment of Chemistry, University of Chicago, Chicago, Illinois 60637, United States.ORCID 0000-0002-6240-3759
Kate A JesseDepartment of Chemistry, University of Chicago, Chicago, Illinois 60637, United States.ORCID 0000-0002-3527-4007
Sophie W AnferovDepartment of Chemistry, University of Chicago, Chicago, Illinois 60637, United States.ORCID 0000-0003-3972-5845
Alexander S FilatovDepartment of Chemistry, University of Chicago, Chicago, Illinois 60637, United States.ORCID 0000-0002-8378-1994
David A MazziottiDepartment of Chemistry, University of Chicago, Chicago, Illinois 60637, United States.ORCID 0000-0002-9938-3886
John S AndersonDepartment of Chemistry, University of Chicago, Chicago, Illinois 60637, United States.ORCID 0000-0002-0730-3018

Funding

Equipment Supplement: Distal Anion Stabilization of Biologically Relevant Oxo IntermediatesR35GM133470 · NIGMS · UNIVERSITY OF CHICAGO · PI ANDERSON, JOHN STUART · 2019 to 2023
$2.1M
NIGMS NIH HHS R35 GM133470
6 · The paper itself

Abstract

Cu systems feature prominently in aerobic oxidative catalysis in both biology and synthetic chemistry. Metal ligand cooperativity is a common theme in both areas as exemplified by galactose oxidase and by aminoxyl radicals in alcohol oxidations. This has motivated investigations into the aerobic chemistry of Cu and specifically the isolation and study of Cu-superoxo species that are invoked as key catalytic intermediates. While several examples of complexes that model biologically relevant Cu(II) superoxo intermediates have been reported, they are not typically competent aerobic catalysts. Here, we report a new Cu complex of the redox-active ligand

Indexed as

CopperOxygenCatalysisLigandsOxidation-ReductionOxidative StressCopperLigandsOxygen

Identifiers

PMID35977083
PMCPMC10017013

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.