ArticleChemical science2022
Excited-state palladium-catalysed reductive alkylation of imines: scope and mechanism.
Article in Chemical science, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
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Who cites it
9 citing papers in PubMed.
- Photoinduced Palladium-Catalyzed Site-Selective Meta-Alkylation of Pyridines.Angewandte Chemie (International ed. in English) · 2026Article
- Article
- Capturing the Hybrid Palladium(I)-Radical Pair Relevant to Photoexcited Palladium Catalysis.Journal of the American Chemical Society · 2025Article
- Modular synthesis of PAHs from aryl halides and terminal alkynes via photoinduced palladium catalysis.Nature communications · 2025Article
- Nucleophilic Additions of Organolithium Reagents to Heterocyclic Aldimines.Synlett : accounts and rapid communications in synthetic organic chemistry · 2025Article
- Illuminating Palladium Catalysis.Accounts of chemical research · 2025Article
- Photocatalytic Decarboxylative Alkylation of Cyclic Imine-BFJournal of the American Chemical Society · 2024Article
- Recent Advances in Visible Light Induced Palladium Catalysis.Angewandte Chemie (International ed. in English) · 2024Review
- Mechanistic insights into excited-state palladium catalysis for C-S bond formations and dehydrogenative sulfonylation of amines.Nature communications · 2023Article
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Authors and funding
3 authors.
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Abstract
Palladium catalysis induced by visible-light irradiation is a promising tool for promoting unusual chemical transformations. We describe the development of excited-state palladium-catalyzed reductive alkylation of imines with alkyl bromides. The new methodology shows broad functional group tolerance and can additionally be applied in the direct three-component reaction of aldehydes, anilines, and alkyl bromides to give the alkyl amines under mild reaction conditions. Time-resolved photoluminescence experiments allowed the determination of the excited-state reaction kinetics and indicate that the reaction is proceeding
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Registered trials
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