ReviewInternational journal of molecular sciences2022
The Pnictogen Bond, Together with Other Non-Covalent Interactions, in the Rational Design of One-, Two- and Three-Dimensional Organic-Inorganic Hybrid Metal Halide Perovskite Semiconducting Materials, and Beyond.
Review in International journal of molecular sciences, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed.
- Nanoscale Electromechanical and Conductive Properties of a Layered Two-Dimensional Hybrid Perovskite.International journal of molecular sciences · 2026Article
- Molecular Electrostatic Surface Potential: A Predictive Framework for Noncovalent Interactions and Adsorption Characteristics in Molecular Entities.International journal of molecular sciences · 2026Review
- Stability Analysis and Optoelectronic Properties of MgACS omega · 2026Article
- Orthorhombic lead-free hybrid perovskite CHRSC advances · 2024Article
- Halogen Bond via an Electrophilic π-Hole on Halogen in Molecules: Does It Exist?International journal of molecular sciences · 2024Article
- Computational applications for the discovery of novel antiperovskites and chalcogenide perovskites: a review.Frontiers in chemistry · 2024Review
- Methylammonium Tetrel Halide Perovskite Ion Pairs and Their Dimers: The Interplay between the Hydrogen-, Pnictogen- and Tetrel-Bonding Interactions.International journal of molecular sciences · 2023Article
- The Tetrel Bond and Tetrel Halide Perovskite Semiconductors.International journal of molecular sciences · 2023Article
- The Effects of Mono- and Bivalent Linear Alkyl Interlayer Spacers on the Photobehavior of Mn(II)-Based Perovskites.International journal of molecular sciences · 2023Article
- Tetrel Bonding in Anion Recognition: A First Principles Investigation.Molecules (Basel, Switzerland) · 2022Article
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Authors and funding
4 authors.
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Abstract
The pnictogen bond, a somewhat overlooked supramolecular chemical synthon known since the middle of the last century, is one of the promising types of non-covalent interactions yet to be fully understood by recognizing and exploiting its properties for the rational design of novel functional materials. Its bonding modes, energy profiles, vibrational structures and charge density topologies, among others, have yet to be comprehensively delineated, both theoretically and experimentally. In this overview, attention is largely centered on the nature of nitrogen-centered pnictogen bonds found in organic-inorganic hybrid metal halide perovskites and closely related structures deposited in the Cambridge Structural Database (CSD) and the Inorganic Chemistry Structural Database (ICSD). Focusing on well-characterized structures, it is shown that it is not merely charge-assisted hydrogen bonds that stabilize the inorganic frameworks, as widely assumed and well-documented, but simultaneously nitrogen-centered pnictogen bonding, and, depending on the atomic constituents of the organic cation, other non-covalent interactions such as halogen bonding and/or tetrel bonding, are also contributors to the stabilizing of a variety of materials in the solid state. We have shown that competition between pnictogen bonding and other interactions plays an important role in determining the tilting of the MX
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