ArticleNature chemistry2022
Different timescales during ultrafast stilbene isomerization in the gas and liquid phases revealed using time-resolved photoelectron spectroscopy.
Article in Nature chemistry, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
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Who cites it
12 citing papers in PubMed.
- Photo-Responsive Functional Hydrogels: Mechanism, Design, and Application.Chemistry, an Asian journal · 2026Review
- Ultrafast solvent-modulated roaming mechanism in bromoform revealed by femtosecond X-ray solution scattering.Nature communications · 2026Article
- Critical Assessment of Curvature-Driven Surface Hopping Algorithms.Journal of chemical theory and computation · 2025Article
- Retrieval of Genuine Ultraviolet Liquid-Microjet Photoelectron Spectra.The journal of physical chemistry. A · 2025Article
- Tipping the ultrafast photochemical balance of cis-stilbene.Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology · 2025Article
- Ultrafast spectroscopy of liquids using extreme-ultraviolet to soft-X-ray pulses.Nature reviews. Chemistry · 2025Review
- Sensitivity Analysis in Photodynamics: How Does the Electronic Structure ControlJournal of chemical theory and computation · 2024Article
- Sub-20-fs UV-XUV beamline for ultrafast molecular spectroscopy.Scientific reports · 2024Article
- What Controls the Quality of Photodynamical Simulations? Electronic Structure Versus Nonadiabatic Algorithm.Journal of chemical theory and computation · 2023Article
- In situ observation of a stepwise [2 + 2] photocycloaddition process using fluorescence spectroscopy.Nature communications · 2023Article
- HNature communications · 2023Article
- Ab Initio Simulation of the Ultrafast Circular Dichroism Spectrum of Provitamin D Ring-Opening.The journal of physical chemistry letters · 2023Article
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Authors and funding
10 authors.
Funding
Abstract
Directly contrasting ultrafast excited-state dynamics in the gas and liquid phases is crucial to understanding the influence of complex environments. Previous studies have often relied on different spectroscopic observables, rendering direct comparisons challenging. Here, we apply extreme-ultraviolet time-resolved photoelectron spectroscopy to both gaseous and liquid cis-stilbene, revealing the coupled electronic and nuclear dynamics that underlie its isomerization. Our measurements track the excited-state wave packets from excitation along the complete reaction path to the final products. We observe coherent excited-state vibrational dynamics in both phases of matter that persist to the final products, enabling the characterization of the branching space of the S
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