Evidence map›Paper›PMID 35948515›Full record

ArticleChemistry (Weinheim an der Bergstrasse, Germany)2022

Microscopic Reactivity of Phenylferrate Ions toward Organyl Halides.

Stefan Lülf, Luxuan Guo, Tobias Parchomyk, Jeremy N Harvey, Konrad Koszinowski

Abstract read
In one paragraph

Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Microscopic Reactivity of Phenylferrate Ions toward Organyl Halides.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Stefan LülfInstitut für Organische und Biomolekulare Chemie, Universität Göttingen, Tammannstr. 2, 37077, Göttingen, Germany.
Luxuan GuoDepartment of Chemistry, KU Leuven, Celestijnenlaan 200F, B-3001, Leuven, Belgium.
Tobias ParchomykInstitut für Organische und Biomolekulare Chemie, Universität Göttingen, Tammannstr. 2, 37077, Göttingen, Germany.
Jeremy N HarveyDepartment of Chemistry, KU Leuven, Celestijnenlaan 200F, B-3001, Leuven, Belgium.ORCID http://orcid.org/0000-0002-1728-1596
Konrad KoszinowskiInstitut für Organische und Biomolekulare Chemie, Universität Göttingen, Tammannstr. 2, 37077, Göttingen, Germany.ORCID http://orcid.org/0000-0001-7352-5789

Funding

China Scholarship CouncilDeutsche Forschungsgemeinschaft KO2875/10
6 · The paper itself

Abstract

Despite its practical importance, organoiron chemistry remains poorly understood due to its mechanistic complexity. Here, we focus on the oxidative addition of organyl halides to phenylferrate anions in the gas phase. By mass-selecting individual phenylferrate anions, we can determine the effect of the oxidation state, the ligation, and the nuclearity of the iron complex on its reactions with a series of organyl halides RX. We find that Ph

Indexed as

cross-coupling reactionsdensity functional calculationsironmass spectrometryreaction mechanisms

Identifiers

PMID35948515
PMCPMC9826238

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.