ArticleJournal of the American Chemical Society2022
Mechanistic Investigations into Amination of Unactivated Arenes via Cation Radical Accelerated Nucleophilic Aromatic Substitution.
Article in Journal of the American Chemical Society, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
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Who cites it
17 citing papers in PubMed, 54 citations in OpenAlex.
- Selenoxanthylium Salts─Organic Photocatalysts for Low-Energy Photoredox Catalysis.Journal of the American Chemical Society · 2026Article
- Diverse radical C-F functionalizations of hexa- to difluoroarenes using boryl radicals as link-and-lose mediators.Nature chemistry · 2026Article
- Deoxyradiofluorination of Phenols via a Difluoromethoxy Nucleofuge Enabled by Organic Photoredox Catalysis.ACS central science · 2026Article
- Visible-Light SThe Journal of organic chemistry · 2025Article
- Light-promoted aromatic denitrative chlorination.Nature chemistry · 2025Article
- Photoredox-Catalyzed Nucleophilic Aromatic Substitution of Halophenols with Azoles via Oligomeric Phenylene Oxide Radicals.Journal of the American Chemical Society · 2025Article
- EDA photochemistry using continuous flow.Journal of flow chemistry · 2025Review
- Catalytic Concerted SJournal of the American Chemical Society · 2024Article
- Acridine/Lewis Acid Complexes as Powerful Photocatalysts: A Combined Experimental and Mechanistic Study.ACS catalysis · 2024Article
- One-Step Synthesis of [ACS central science · 2024Article
- Amination of Phenols and Halophenols via Pyridinium-Iridium Dual Photocatalysis.ACS catalysis · 2024Article
- Unlocking flavin photoacid catalysis through electrophotochemistry.Chemical science · 2024Article
- Alkoxy Radical Generation Mediated by Sulfoxide Cation Radicals for Alcohol-Directed Aliphatic C-H Functionalization.Journal of the American Chemical Society · 2024Article
- Oxidative two-state photoreactivity of a manganese(IV) complex using near-infrared light.Nature chemistry · 2024Article
- Synthesis of Phenol-Pyridinium Salts Enabled by Tandem Electron Donor-Acceptor Complexation and Iridium Photocatalysis.The Journal of organic chemistry · 2024Article
- Triplet quenching pathway control with molecular dyads enables the identification of a highly oxidizing annihilator class.Chemical science · 2023Article
- Visible-light acridinium-based organophotoredox catalysis in late-stage synthetic applications.RSC advances · 2023Review
Corrections and comments
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Authors and funding
3 authors at 1 institution in 1 country.
Funding
Abstract
A mechanistic investigation into the amination of electron-neutral and electron-rich arenes using organic photoredox catalysis is presented. Kinetic and computational data support rate-limiting nucleophilic addition into an arene cation radical using both azole and primary amine nucleophiles. This finding is consistent with both fluoride and alkoxide nucleofuges, supporting a unified mechanistic picture using cation radical accelerated nucleophilic aromatic substitution (CRA-S
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Registered trials
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