Evidence map›Paper›PMID 35944124›Full record

ArticleChemphyschem : a European journal of chemical physics and physical chemistry2022

The Influence of Deuterium Isotope Effects on Structural Rearrangements, Ensemble Equilibria, and Hydrogen Bonding in Protic Ionic Liquids.

Alexander E Khudozhitkov, Peter Stange, Dietmar Paschek, Alexander G Stepanov, Daniil I Kolokolov, Ralf Ludwig

Open access · hybridAbstract read
In one paragraph

Article in Chemphyschem : a European journal of chemical physics and physical chemistry, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
0.3field-weighted citation impact, top 55% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed, 6 citations in OpenAlex.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors at 4 institutions in 2 countries.

Alexander E KhudozhitkovBoreskov Institute of Catalysis, Siberian Branch of Russian Academy of Sciences, Prospekt Akademika Lavrentieva 5, Novosibirsk, 630090, Russia.
Peter StangeUniversität Rostock, Institut für Chemie, Abteilung für Physikalische Chemie, Albert-Einstein-Straße 27, 18059, Rostock, Germany.ORCID 0000-0002-0759-9461
Dietmar PaschekUniversität Rostock, Institut für Chemie, Abteilung für Physikalische Chemie, Albert-Einstein-Straße 27, 18059, Rostock, Germany.ORCID 0000-0002-0342-324X
Alexander G StepanovBoreskov Institute of Catalysis, Siberian Branch of Russian Academy of Sciences, Prospekt Akademika Lavrentieva 5, Novosibirsk, 630090, Russia.ORCID 0000-0003-2754-5273
Daniil I KolokolovBoreskov Institute of Catalysis, Siberian Branch of Russian Academy of Sciences, Prospekt Akademika Lavrentieva 5, Novosibirsk, 630090, Russia.ORCID 0000-0002-1434-095X
Ralf LudwigUniversität Rostock, Institut für Chemie, Abteilung für Physikalische Chemie, Albert-Einstein-Straße 27, 18059, Rostock, Germany.ORCID 0000-0002-8549-071X
Novosibirsk State University · RUUniversity of Rostock · DEBoreskov Institute of Catalysis · RULeibniz Institute for Catalysis · DE

Funding

Deutsche Forschungsgemeinschaft (DFG) 401427621Deutsche Forschungsgemeinschaft (DFG) 506/15-1Humboldt Foundation (AvH)Russian Science Foundation 21-13-00047
6 · The paper itself

Abstract

We report strong isotope effects for the protic ionic liquid triethylammonium methanesulfonate [TEA][OMs] by means of deuterium solid-state NMR spectroscopy covering broad temperature ranges from 65 K to 313 K. Both isotopically labelled PILs differ in non-deuterated and fully deuterated ethyl groups of the triethyl ammonium cations. The N-D bond of both cations is used as sensitive probe for hydrogen bonding and structural ordering. The

Indexed as

Ionic LiquidsCationsDeuteriumHydrogen BondingMagnetic Resonance SpectroscopyCationsDeuteriumIonic Liquidsheterogeneitieshydrogen bondingionic liquidsIsotope effectssolid-stateNMR

Identifiers

PMID35944124
PMCPMC10087857
OpenAlexW4292457893

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.