ArticleNature communications2022
Insights into the activity of nickel boride/nickel heterostructures for efficient methanol electrooxidation.
Article in Nature communications, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 35 papers.
What it found
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Who cites it
35 citing papers in PubMed, 435 citations in OpenAlex.
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- Unraveling the hidden conditions in NiOOH for electrocatalytic oxidation of methanol to formaldehyde with unity Faraday efficiency and selectivity.Chemical science · 2026Article
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- Charge symmetry breaking stabilizes high-valence Ru sites for proton exchange membrane electrolysis.Nature communications · 2026Article
- Harnessing Transformation of Metal-Ligand Coordination in Dinuclear Ni(II)-Schiff Base Coordination Polymer for Promoting Electrochemical Oxygen Evolution.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
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- Ce Single Atom-Engineered Amorphous/Crystalline Nanosheets for Enhanced Alkaline Water Electrolysis.Advanced materials (Deerfield Beach, Fla.) · 2025Article
- Dynamics in electrochemical organic oxidation reactions from in situ and operando techniques.Nature reviews. Chemistry · 2025Review
- Dynamic construction of a durable epitaxial catalytic layer for industrial alkaline water splitting.Nature communications · 2025Article
- Geography-guided industrial-level upcycling of polyethylene terephthalate plastics through alkaline seawater-based processes.Science advances · 2025Article
- Stable Ni(II) sites in Prussian blue analogue for selective, ampere-level ethylene glycol electrooxidation.Nature communications · 2025Article
- Methanol-Enhanced Low-Cell-Voltage Hydrogen Generation at Industrial-Grade Current Density by Triadic Active Sites of PtJournal of the American Chemical Society · 2025Article
- Fine-tuning d-p hybridization in Ni-BNature communications · 2025Article
- Optimizing surface active sites via burying single atom into subsurface lattice for boosted methanol electrooxidation.Nature communications · 2025Article
- Parameterization and quantification of two key operando physio-chemical descriptors for water-assisted electro-catalytic organic oxidation.Nature communications · 2024Article
Corrections and comments
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Authors and funding
7 authors at 2 institutions in 1 country.
Funding
Abstract
Designing efficient catalysts and understanding the underlying mechanisms for anodic nucleophile electrooxidation are central to the advancement of electrochemically-driven technologies. Here, a heterostructure of nickel boride/nickel catalyst is developed to enable methanol electrooxidation into formate with a Faradaic efficiency of nearly 100%. Operando electrochemical impedance spectroscopy and in situ Raman spectroscopy are applied to understand the influence of methanol concentration in the methanol oxidation reaction. High concentrations of methanol inhibit the phase transition of the electrocatalyst to high-valent electro-oxidation products, and electrophilic oxygen species (O* or OH*) formed on the electrocatalyst are considered to be the catalytically active species. Additional mechanistic investigation with density functional theory calculations reveals that the potential-determining step, the formation of *CH
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.