ArticleNature communications2022
Large breathing effect in ZIF-65(Zn) with expansion and contraction of the SOD cage.
Article in Nature communications, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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Who cites it
8 citing papers in PubMed.
- Photo Capture of Water by Single Crystals of a Nonporous Metal-Organic Material.Journal of the American Chemical Society · 2026Article
- Deciphering the guest-free crystal structures and thermal breathing of the flexible metal-organic frameworks ZIF-7 and ZIF-9.Chemical science · 2026Article
- Plastic Pores for Switchable and Optimized Adsorption Behaviors.ACS central science · 2025Article
- Modeling Gas Adsorption and Mechanistic Insights into Flexibility in Isoreticular Metal-Organic Frameworks Using High-Dimensional Neural Network Potentials.Langmuir : the ACS journal of surfaces and colloids · 2025Article
- Structural Features, Chemical Diversity, and Physical Properties of Microporous Sodalite-Type Materials: A Review.International journal of molecular sciences · 2024Review
- Template Role of Long Alkyl-Chain Amides in the Synthesis of Zeolitic Imidazolate Frameworks.ACS omega · 2024Article
- Evolution of the Structure and Morphology of Dual-Linker ZIF-301-eIm.Molecules (Basel, Switzerland) · 2024Article
- Zeolitic imidazolate framework-8: a versatile nanoplatform for tissue regeneration.Frontiers in bioengineering and biotechnology · 2024Review
Corrections and comments
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Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The flexibility and guest-responsive behavior of some metal-organic frameworks (MOFs) indicate their potential in the fields of sensors and molecular recognition. As a subfamily of MOFs, the flexible zeolitic imidazolate frameworks (ZIFs) typically feature a small displacive transition due to the rigid zeolite topology. Herein, an atypical reversible displacive transition (6.4 Å) is observed for the sodalite (SOD) cage in flexible ZIF-65(Zn), which represents an unusually large breathing effect compared to other ZIFs. ZIF-65(Zn) exhibits a stepwise II → III → I expansion between an unusual ellipsoidal SOD cage (8.6 Å × 15.9 Å for II) and a spherical SOD cage (15.0 Å for I). The breathing behavior of ZIF-65(Zn) varies depending on the nature of the guest molecules (polarity and shape). Computational simulations are employed to rationalize the differences in the breathing behavior depending on the structure of the ZIF-65(Zn) cage and the nature of the guest-associated host-guest and guest-guest interactions.
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