Evidence map›Paper›PMID 35926979›Full record

ArticleInorganic chemistry2022

Noncovalent Assembly and Catalytic Activity of Hybrid Materials Based on Pd Complexes Adsorbed on Multiwalled Carbon Nanotubes, Graphene, and Graphene Nanoplatelets.

Alba M Valbuena-Rus, Matteo Savastano, Paloma Arranz-Mascarós, Carla Bazzicalupi, María P Clares, María L Godino-Salido, María D Gutiérrez-Valero, Mario Inclán, Antonio Bianchi, Enrique García-España and 1 more

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Inorganic chemistry, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Alba M Valbuena-RusDepartment of Inorganic and Organic Chemistry, University of Jaén, 23071 Jaen, Spain.
Matteo SavastanoDepartment of Chemistry "Ugo Schiff", University of Florence, Via della Lastruccia 3-13, 50019 Sesto Fiorentino, Italy.ORCID 0000-0002-9780-7542
Paloma Arranz-MascarósDepartment of Inorganic and Organic Chemistry, University of Jaén, 23071 Jaen, Spain.ORCID 0000-0002-3693-5997
Carla BazzicalupiDepartment of Chemistry "Ugo Schiff", University of Florence, Via della Lastruccia 3-13, 50019 Sesto Fiorentino, Italy.ORCID 0000-0003-4602-0405
María P ClaresICMol, Department of Inorganic Chemistry, University of Valencia, C/Catedrático José Beltrán 2, 46980 Paterna, Spain.
María L Godino-SalidoDepartment of Inorganic and Organic Chemistry, University of Jaén, 23071 Jaen, Spain.ORCID 0000-0003-3257-4431
María D Gutiérrez-ValeroDepartment of Inorganic and Organic Chemistry, University of Jaén, 23071 Jaen, Spain.ORCID 0000-0002-7460-0143
Mario InclánICMol, Department of Inorganic Chemistry, University of Valencia, C/Catedrático José Beltrán 2, 46980 Paterna, Spain.
Antonio BianchiDepartment of Chemistry "Ugo Schiff", University of Florence, Via della Lastruccia 3-13, 50019 Sesto Fiorentino, Italy.ORCID 0000-0002-1082-3911
Enrique García-EspañaICMol, Department of Inorganic Chemistry, University of Valencia, C/Catedrático José Beltrán 2, 46980 Paterna, Spain.ORCID 0000-0002-4601-6505
Rafael López-GarzónDepartment of Inorganic and Organic Chemistry, University of Jaén, 23071 Jaen, Spain.ORCID 0000-0001-7176-1913

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Green catalysts with excellent performance in Cu-free Sonogashira coupling reactions can be prepared by the supramolecular decoration of graphene surfaces with Pd(II) complexes. Here we report the synthesis, characterization, and catalytic properties of new catalysts obtained by the surface decoration of multiwalled carbon nanotubes (MWCNTs), graphene (G), and graphene nanoplatelets (GNPTs) with Pd(II) complexes of tetraaza-macrocyclic ligands bearing one or two anchor functionalities. The decoration of these carbon surfaces takes place under environmentally friendly conditions (water, room temperature, aerobic) in two steps: (i) π-π stacking attachment of the ligand via electron-poor anchor group 6-amino-3,4-dihydro-3-methyl-5-nitroso-4-oxo-pyrimidine and (ii) Pd(II) coordination from PdCl

Identifiers

PMID35926979
PMCPMC9387097

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.