ArticleAngewandte Chemie (International ed. in English)2022
Calix[4]pyrrolato Stibenium: Lewis Superacidity by Antimony(III)-Antimony(V) Electromerism.
Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
What it found
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Who cites it
8 citing papers in PubMed.
- T-Shaped Stibenium(III) Cation: Hydrostibination Without Sb─H Bond.Angewandte Chemie (International ed. in English) · 2026Article
- Structurally Constrained Stibenium: Metallomimetic C-Si Bond Activation.Angewandte Chemie (International ed. in English) · 2026Article
- Directed trilithiation enables entropically stabilized heavy-atom-centered triangulenes.Nature communications · 2026Article
- Isolation and Reactivity of a Square-Planar Trisamido Silane.Angewandte Chemie (International ed. in English) · 2026Article
- Lewis Acidity of the SbClAngewandte Chemie (International ed. in English) · 2025Article
- Isolation of a Square Pyramidal Bis(amidophenolate)-Supported As(III)-Cation: Coordination-Induced Electromerism at As.Angewandte Chemie (International ed. in English) · 2025Article
- Calix[4]pyrrolato-germane-(thf)Journal of the American Chemical Society · 2023Article
- Calix[4]pyrrolato Stibenium: Lewis Superacidity by Antimony(III)-Antimony(V) Electromerism.Angewandte Chemie (International ed. in English) · 2022Article
Corrections and comments
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Authors and funding
4 authors.
Funding
Abstract
Lewis superacids enable the activation of highly inert substrates. However, the permanent presence of a Lewis superacidic center comes along with a constantly increased intolerance toward functional groups or ambient conditions. Herein, we describe a strategy to unleash Lewis superacidity by electromerism. Experimental and computational results indicate that coordinating a Lewis base to Δ-calix[4]pyrrolato-antimony(III) triggers a ligand redox-noninnocent coupled transfer into antimony(V)-state that exhibits Lewis superacidic features. Lewis acidity by electromerism establishes a concept of potential generality for powerful yet robust reagents and on-site substrate activation approaches.
Indexed as
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.