ArticleNature communications2022
Selective separation of light rare-earth elements by supramolecular encapsulation and precipitation.
Article in Nature communications, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
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Who cites it
14 citing papers in PubMed.
- Macrocyclic Chelators for Aqueous Lanthanide Separations via Precipitation: Toward Sustainable Recycling of Rare-Earths from NdFeB Magnets.Journal of the American Chemical Society · 2025Article
- 18-membered macrocycle appended on resin for selective rare earth element extraction and separation.Communications chemistry · 2025Article
- On the Importance of Configuration Search to the Predictivity of Lanthanide Selectivity.JACS Au · 2025Article
- Modulating metal-centered dimerization of a lanthanide chaperone protein for separation of light lanthanides.Proceedings of the National Academy of Sciences of the United States of America · 2024Article
- Tetradentate Ligand's Chameleon-Like Behavior Offers Recognition of Specific Lanthanides.Journal of the American Chemical Society · 2024Article
- Drivers and Pathways for the Recovery of Critical Metals from Waste-Printed Circuit Boards.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Review
- Selective Gold Precipitation by a Tertiary Diamide Driven by Thermodynamic Control.Inorganic chemistry · 2024Article
- Insights into coordination and ligand trends of lanthanide complexes from the Cambridge Structural Database.Scientific reports · 2024Article
- Siloxide tripodal ligands as a scaffold for stabilizing lanthanides in the +4 oxidation state.Chemical science · 2024Article
- Article
- Noncovalent interaction guided selectivity of haloaromatic isomers in a flexible porous coordination polymer.Chemical science · 2023Article
- High-efficiency gold recovery by additive-induced supramolecular polymerization of β-cyclodextrin.Nature communications · 2023Article
- Article
- Semirigid Ligands Enhance Different Coordination Behavior of Nd and Dy Relevant to Their Separation and Recovery in a Non-aqueous Environment.Inorganic chemistry · 2022Article
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Supramolecular chemical strategies for Rare Earth (RE) element separations are emerging which amplify the small changes in properties across the series to bias selectivity in extraction or precipitation. These advances are important as the REs are crucial to modern technologies yet their extraction, separation, and recycling using conventional techniques remain challenging. We report here a pre-organised triamidoarene platform which, under acidic, biphasic conditions, uniquely and selectively precipitates light RE nitratometalates as supramolecular capsules. The capsules exhibit both intra- and intermolecular hydrogen bonds that dictate selectivity, promote precipitation, and facilitate the straightforward release of the RE and recycling of the receptor. This work provides a self-assembly route to metal separations that exploits size and shape complementarity and has the potential to integrate into conventional processes due to its compatibility with acidic metal feed streams.
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