Evidence map›Paper›PMID 35918327›Full record

ArticleNature communications2022

Steering the multiexciton generation in slip-stacked perylene dye array via exciton coupling.

Yongseok Hong, Maximilian Rudolf, Munnyon Kim, Juno Kim, Tim Schembri, Ana-Maria Krause, Kazutaka Shoyama, David Bialas, Merle I S Röhr, Taiha Joo and 3 more

Abstract read
In one paragraph

Article in Nature communications, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.

0numbers the graph read from it
0cells of the map it votes in
16citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

16 citing papers in PubMed.

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  14. Modeling Singlet Fission on a Quantum Computer.The journal of physical chemistry letters · 2023
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

13 authors.

Yongseok HongSpectroscopy Laboratory for Functional π-Electronic Systems and Department of Chemistry, Yonsei University, Seoul, 03722, Republic of Korea.ORCID http://orcid.org/0000-0002-8095-3148
Maximilian RudolfUniversitat Würzburg, Institut für Organische Chemie, Am Hubland, 97074, Würzburg, Germany.
Munnyon KimDepartment of Chemistry, Pohang University of Science and Technology (POSTECH), Pohang, 37673, Republic of Korea.
Juno KimSpectroscopy Laboratory for Functional π-Electronic Systems and Department of Chemistry, Yonsei University, Seoul, 03722, Republic of Korea.ORCID http://orcid.org/0000-0002-1477-3296
Tim SchembriUniversität Würzburg, Center for Nanosystems Chemistry, Theodor-Boveri Weg, 97074, Würzburg, Germany.
Ana-Maria KrauseUniversität Würzburg, Center for Nanosystems Chemistry, Theodor-Boveri Weg, 97074, Würzburg, Germany.
Kazutaka ShoyamaUniversität Würzburg, Center for Nanosystems Chemistry, Theodor-Boveri Weg, 97074, Würzburg, Germany.ORCID http://orcid.org/0000-0003-0937-4431
David BialasUniversitat Würzburg, Institut für Organische Chemie, Am Hubland, 97074, Würzburg, Germany.
Merle I S RöhrUniversität Würzburg, Center for Nanosystems Chemistry, Theodor-Boveri Weg, 97074, Würzburg, Germany. merle.roehr@uni-wuerzburg.de.ORCID http://orcid.org/0000-0002-2128-3498
Taiha JooDepartment of Chemistry, Pohang University of Science and Technology (POSTECH), Pohang, 37673, Republic of Korea. thjoo@postech.ac.kr.ORCID http://orcid.org/0000-0003-2690-7789
Hyungjun KimDepartment of Chemistry and Research Institute of Basic Sciences, Incheon National University, Incheon, 22012, Republic of Korea. kim.hyungjun@inu.ac.kr.ORCID http://orcid.org/0000-0002-7204-3718
Dongho KimSpectroscopy Laboratory for Functional π-Electronic Systems and Department of Chemistry, Yonsei University, Seoul, 03722, Republic of Korea. dongho@yonsei.ac.kr.ORCID http://orcid.org/0000-0001-8668-2644
Frank WürthnerUniversitat Würzburg, Institut für Organische Chemie, Am Hubland, 97074, Würzburg, Germany. wuerthner@uni-wuerzburg.de.ORCID http://orcid.org/0000-0001-7245-0471

Funding

Deutsches Elektronen-Synchrotron (DESY) STP-20010322Korea Institute of Science and Technology Information (KISTI) KSC-2019-CRE-0201National Research Foundation of Korea (NRF) 2020R1A5A1019141National Research Foundation of Korea (NRF) 2021R1A2C300630811
6 · The paper itself

Abstract

Dye arrays from dimers up to larger oligomers constitute the functional units of natural light harvesting systems as well as organic photonic and photovoltaic materials. Whilst in the past decades many photophysical studies were devoted to molecular dimers for deriving structure-property relationship to unravel the design principles for ideal optoelectronic materials, they fail to accomplish the subsequent processes of charge carrier generation or the detachment of two triplet species in singlet fission (SF). Here, we present a slip-stacked perylene bisimide trimer, which constitutes a bridge between hitherto studied dimer and solid-state materials, to investigate SF mechanisms. This work showcases multiple pathways towards the multiexciton state through direct or excimer-mediated mechanisms by depending upon interchromophoric interaction. These results suggest the comprehensive role of the exciton coupling, exciton delocalization, and excimer state to facilitate the SF process. In this regard, our observations expand the fundamental understanding the structure-property relationship in dye arrays.

Identifiers

PMID35918327
PMCPMC9345863

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.