Evidence map›Paper›PMID 35916208›Full record

ArticleChemistry (Weinheim an der Bergstrasse, Germany)2022

Branched Tertiary Amines from Aldehydes and α-Olefins by Combined Multiphase Tandem Reactions.

Marc Strohmann, Andreas J Vorholt, Walter Leitner

Open access · hybridAbstract read
In one paragraph

Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
0.3field-weighted citation impact, top 53% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed, 4 citations in OpenAlex.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors at 1 institution in 1 country.

Marc StrohmannMultiphase Catalysis, Max-Planck-Institut für Chemische Energiekonversion, Stiftstraße 34-36, 45470, Mülheim an der Ruhr, Germany.
Andreas J VorholtMultiphase Catalysis, Max-Planck-Institut für Chemische Energiekonversion, Stiftstraße 34-36, 45470, Mülheim an der Ruhr, Germany.ORCID http://orcid.org/0000-0001-9302-2273
Walter LeitnerMultiphase Catalysis, Max-Planck-Institut für Chemische Energiekonversion, Stiftstraße 34-36, 45470, Mülheim an der Ruhr, Germany.ORCID http://orcid.org/0000-0001-6100-9656
Max Planck Institute for Chemical Energy Conversion · DE

Funding

Max-Planck-Gesellschaft
6 · The paper itself

Abstract

This study presents the transformation of olefins to branched amines by combining a hydroformylation/aldol condensation tandem reaction with the reductive amination in a combined multiphase system that can be recycled 9 times. The products are branched amines that are precursors for surfactants. Since the multiphase hydrofomylation/aldol condensation system has already been studied, the first step was to develop the partial hydrogenation of unsaturated aldehydes together with a subsequent reductive amination. The rhodium/phosphine catalyst is immobilized in a polar polyethylene phase which separates from the product phase after the reaction. Reaction and catalyst recycling are demonstrated by the conversion of the C

Indexed as

AlkenesRhodiumAldehydesAminesCarbon MonoxideCatalysisDimethylaminesPolyethylenesStereoisomerismSurface-Active Agents3-hydroxybutanalAldehydesAlkenesAminesCarbon MonoxideDimethylaminesPolyethylenesRhodiumSurface-Active Agentsaminationhomogeneous catalysisrhodium

Identifiers

PMID35916208
PMCPMC9804909
OpenAlexW4289523806

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC-ND
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.