ArticleNature chemistry2022
σ-σ Stacked supramolecular junctions.
Article in Nature chemistry, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 22 papers.
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Who cites it
22 citing papers in PubMed.
- Machine Learning-Enhanced Molecular Dynamics of 4,4'-Bipyridine in a Break Junction: A Supramolecular Origin of the High Conductance.ACS nanoscience Au · 2026Article
- Solvent Environment Influences Molecular Conformation and Electron Transport in Peptides.The journal of physical chemistry letters · 2026Article
- Fingerprint Recognition Based on Molecular-Scale Conductance Response via Electrochemically Gated Quantum Tunnelling.Sensors (Basel, Switzerland) · 2026Article
- Sustained hydrogen peroxide production via MXene-functionalized supramolecular docking.Nature communications · 2026Article
- Odd-even conductance oscillations inScience advances · 2026Article
- Probing Ultrastrong Through-Space Electronic Coupling in Donor-Acceptor Systems at the Single-Molecule Level.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Electronic Coupling of Molecular Complexes to Au Electrodes Mediated via Host-Guest Interactions.Journal of the American Chemical Society · 2026Article
- Effect of hydrogen migration on the electronic structure of phenol derivatives observed by single-molecule conductance.Nature communications · 2025Article
- Molecular electronic devices based on atomic manufacturing methods.Microsystems & nanoengineering · 2025Review
- Long-term stabilization of universal adhesive interfaces in blood-contaminated dentin by myricetin and resveratrol: MMP inhibition, remineralization, and chemical compatibility with 10-MDP after 12 months.Clinical oral investigations · 2025Article
- Article
- Engineering Charge Transport by Tunneling in Supramolecular Assemblies through Precise Control of Metal-Ligand Interactions.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
- Shape-persistent ladder molecules exhibit nanogap-independent conductance in single-molecule junctions.Nature chemistry · 2024Article
- Charge Transport through Single-Molecule Junctions with σ-Delocalized Systems.Journal of the American Chemical Society · 2024Article
- Single-Molecule Electrical Profiling of Peptides and Proteins.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Review
- Methods for the analysis, interpretation, and prediction of single-molecule junction conductance behaviour.Chemical science · 2024Review
- Review
- Chemistry of the Au-Thiol Interface through the Lens of Single-Molecule Flicker Noise Measurements.Journal of the American Chemical Society · 2024Article
- Intramolecular London Dispersion Interactions in Single-Molecule Junctions.Journal of the American Chemical Society · 2024Article
- Delta-T Flicker Noise Demonstrated with Molecular Junctions.Nano letters · 2024Article
Corrections and comments
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Authors and funding
11 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Intermolecular charge transport plays an essential role in organic electronic materials and biological systems. To date, experimental investigations of intermolecular charge transport in molecular materials and electronic devices have been restricted to conjugated systems in which π-π stacking interactions are involved. Herein we demonstrate that the σ-σ stacking interactions between neighbouring non-conjugated molecules offer an efficient pathway for charge transport through supramolecular junctions. The conductance of σ-σ stacked molecular junctions formed between two non-conjugated cyclohexanethiol or single-anchored adamantane molecules is comparable to that of π-π stacked molecular junctions formed between π-conjugated benzene rings. The current-voltage characteristics and flicker noise analysis demonstrate the existence of stacked molecular junctions formed between the electrode pairs and exhibit the characteristics of through-space charge transport. Density functional theory calculations combined with the non-equilibrium Green's function method reveal that efficient charge transport occurs between two molecules configured with σ-σ stacking interactions.
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35902741What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.